Personal profile

Research Interests

Our research involves electron-nuclear double resonance study of metallo-enzymes, long-range electron transfer between proteins, and new macro-cycles for solid-state and biomedical applications.

Training Experience

1966 - 1967Postdoctoral Study at Massachusetts Institute of Technology

Fingerprint Fingerprint is based on mining the text of the person's scientific documents to create an index of weighted terms, which defines the key subjects of each individual researcher.

  • 6 Similar Profiles
Electron Spin Resonance Spectroscopy Medicine & Life Sciences
Electrons Chemical Compounds
Paramagnetic resonance Chemical Compounds
Ligands Chemical Compounds
Spectroscopy Chemical Compounds
Metals Chemical Compounds
Proteins Chemical Compounds
Spectrum Analysis Medicine & Life Sciences

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Research Output 1967 2017

5 Citations

13C ENDOR spectroscopy of lipoxygenase-substrate complexes reveals the structural basis for C-H activation by tunneling

Horitani, M., Offenbacher, A. R., Marcus Carr, C. A., Yu, T., Hoeke, V., Cutsail, G. E., Hammes-Schiffer, S., Klinman, J. P. & Hoffman, B. M. Feb 8 2017 In : Journal of the American Chemical Society. 139, 5, p. 1984-1997 14 p.

Research output: Research - peer-reviewArticle

Chemical activation
Spectroscopy
Hydrogen
Substrates
Lipoxygenase

ENDOR characterization of an iron-alkene complex provides insight into a corresponding organometallic intermediate of nitrogenase

Horitani, M., Grubel, K., McWilliams, S. F., Stubbert, B. D., Mercado, B. Q., Yu, Y., Gurubasavaraj, P. M., Lees, N. S., Holland, P. L. & Hoffman, B. M. 2017 In : Chemical Science. 8, 9, p. 5941-5948 8 p.

Research output: Research - peer-reviewArticle

Nitrogenase
Alkenes
Organometallics
Iron
Spectroscopy
1 Citations

EPR/ENDOR and Theoretical Study of the Jahn-Teller-Active [HIPTN3N]MoVL Complexes (L = N-, NH)

Sharma, A., Roemelt, M., Reithofer, M., Schrock, R. R., Hoffman, B. M. & Neese, F. Jun 19 2017 In : Inorganic Chemistry. 56, 12, p. 6906-6919 14 p.

Research output: Research - peer-reviewArticle

Paramagnetic resonance
Electrons
ground state
protons
electronics

Mechanism of Nitrogenase H2 Formation by Metal-Hydride Protonation Probed by Mediated Electrocatalysis and H/D Isotope Effects

Khadka, N., Milton, R. D., Shaw, S., Lukoyanov, D., Dean, D. R., Minteer, S. D., Raugei, S., Hoffman, B. M. & Seefeldt, L. C. 2017 In : Journal of the American Chemical Society. 139, 38, p. 13518-13524 7 p.

Research output: Research - peer-reviewArticle

Nitrogenase
Electrocatalysis
Protonation
Hydrides
Isotopes

Nitrogenase Mechanism: Electron and Proton Accumulation and N2 Reduction

Seefeldt, L. C., Dean, D. R. & Hoffman, B. M. 2017 Molybdenum and Tungsten Enzymes: Biochemistry. 5 ed. Royal Society of Chemistry, Vol. 2017-January, p. 274-296 23 p. (RSC Metallobiology; vol. 2017-January, no. 5)

Research output: ResearchChapter

Nitrogenase
Protons
Electrons
Nitrogen fixation
Nitrogen Fixation