Personal profile

Research Interests

Our research applies coordination chemistry, which enables the control of geometric and electronic structure at the atomic level, to develop and study functional molecules and materials. More specifically, our research exploits chemical control of spin to synthesize metal-organic radical magnets and magnetic resonance probes that map temperature, redox environment, pH, and ion concentration, and we employ metal-organic frameworks as solid-state matrices to study the structure, bonding, and reactivity of unusual metal complexes relevant to biology and catalysis.

Education / Academic qualification

Chemistry, PhD, University of California, Berkeley

… → 2010

Chemistry, BS, Marshall University

… → 2004

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Ligands Chemical Compounds
Magnets Chemical Compounds
Metals Chemical Compounds
Magnetic susceptibility Chemical Compounds
Exchange coupling Chemical Compounds
Magnetic relaxation Chemical Compounds
Iron Chemical Compounds
Ground state Chemical Compounds

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Research Output 2006 2018

  • 1907 Citations
  • 49 Article
  • 1 Comment/debate
  • 1 Review article

A structurally-characterized peroxomanganese(IV) porphyrin from reversible O2 binding within a metal-organic framework

Gallagher, A. T., Lee, J. Y., Kathiresan, V., Anderson, J. S., Hoffman, B. M. & Harris, T. D. Jan 1 2018 In : Chemical Science. 9, 6, p. 1596-1603 8 p.

Research output: Contribution to journalArticle

Porphyrins
Metals
Paramagnetic resonance
Enthalpy
Metalloporphyrins
16 Citations

2D Conductive Iron-Quinoid Magnets Ordering up to Tc = 105 K via Heterogenous Redox Chemistry

DeGayner, J. A., Jeon, I. R., Sun, L., Dincă, M. & Harris, T. D. Mar 22 2017 In : Journal of the American Chemical Society. 139, 11, p. 4175-4184 10 p.

Research output: Contribution to journalArticle

Magnets
Oxidation-Reduction
Iron
Metals
Temperature
3 Citations

A Porous Array of Clock Qubits

Zadrozny, J. M., Gallagher, A. T., Harris, T. D. & Freedman, D. E. May 24 2017 In : Journal of the American Chemical Society. 139, 20, p. 7089-7094 6 p.

Research output: Contribution to journalArticle

Porous materials
Noise
Clocks
Porosity
Physics

A structurally-characterized zinc 2,5-diiminobenzoquinoid chain compound

Liu, L. & Harris, T. D. Apr 24 2017 In : Inorganica Chimica Acta. 460, p. 108-113 6 p.

Research output: Contribution to journalArticle

Zinc
zinc
ligands
Ligands
organic solids
3 Citations

CO Binding at a Four-Coordinate Cobaltous Porphyrin Site in a Metal-Organic Framework: Structural, EPR, and Gas Adsorption Analysis

Gallagher, A. T., Malliakas, C. D. & Harris, T. D. Apr 17 2017 In : Inorganic Chemistry. 56, 8, p. 4654-4661 8 p.

Research output: Contribution to journalArticle

Gas adsorption
Porphyrins
Carbon Monoxide
porphyrins
Paramagnetic resonance