In this proposal, we will apply chemistry, polymer science, biochemistry, bioengineering, computational modeling, and evolutionary biology tools to engineer the translation apparatus for synthesis of conjugated SDPs via step-growth and condensation polymerization reactions. Our focus in this white paper is on SDPs based on the Knoevenagel condensation, a type of carbonyl addition reaction. The full proposal will describe approaches to other SDP families (e.g., SDPs derived from Julia-Kocienski olefination and transition metal mediated cross-coupling reactions).
|Effective start/end date||7/1/16 → 6/30/22|
- Army Research Office (W911NF-16-1-0372 P00015)
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