1,2-Bis{[3,5-bis(2,6-diisopropylphenyl)phenyl]imino}-acenaphthene toluene monosolvate

Tracy L. Lohr; Warren E. Piers; Masood Parvez

doi:10.1107/S1600536811031242

1,2-Bis{[3,5-bis(2,6-diisopropylphenyl)phenyl]imino}-acenaphthene toluene monosolvate

Tracy L. Lohr, Warren E. Piers, Masood Parvez^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

In the title compound, C ₇₂H ₈₀N ₂· C ₇H ₈, the acenaphthene ring system is essentially planar, with a maximum deviation of 0.041 (3) Å. The benzene rings bonded to the the N atoms are essentially parallel, forming a dihedral angle of 0.80 (11)°, and these rings form dihedral angles of 87.49 (9) and 88.25 (10)° with the mean plane of the acenaphthene ring system. The methyl C atoms of three of the isopropyl groups are disordered of two sets of sites of equal occupancy.

Original language	English (US)
Pages (from-to)	o2280
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	67
Issue number	9
DOIs	https://doi.org/10.1107/S1600536811031242
State	Published - Sep 2011

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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@article{6293073057d7432ea4eb162b1ee39d1e,

title = "1,2-Bis{[3,5-bis(2,6-diisopropylphenyl)phenyl]imino}-acenaphthene toluene monosolvate",

abstract = "In the title compound, C 72H 80N 2· C 7H 8, the acenaphthene ring system is essentially planar, with a maximum deviation of 0.041 (3) {\AA}. The benzene rings bonded to the the N atoms are essentially parallel, forming a dihedral angle of 0.80 (11)°, and these rings form dihedral angles of 87.49 (9) and 88.25 (10)° with the mean plane of the acenaphthene ring system. The methyl C atoms of three of the isopropyl groups are disordered of two sets of sites of equal occupancy.",

author = "Lohr, {Tracy L.} and Piers, {Warren E.} and Masood Parvez",

year = "2011",

month = sep,

doi = "10.1107/S1600536811031242",

language = "English (US)",

volume = "67",

pages = "o2280",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "9",

}

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T1 - 1,2-Bis{[3,5-bis(2,6-diisopropylphenyl)phenyl]imino}-acenaphthene toluene monosolvate

AU - Lohr, Tracy L.

AU - Piers, Warren E.

AU - Parvez, Masood

PY - 2011/9

Y1 - 2011/9

N2 - In the title compound, C 72H 80N 2· C 7H 8, the acenaphthene ring system is essentially planar, with a maximum deviation of 0.041 (3) Å. The benzene rings bonded to the the N atoms are essentially parallel, forming a dihedral angle of 0.80 (11)°, and these rings form dihedral angles of 87.49 (9) and 88.25 (10)° with the mean plane of the acenaphthene ring system. The methyl C atoms of three of the isopropyl groups are disordered of two sets of sites of equal occupancy.

AB - In the title compound, C 72H 80N 2· C 7H 8, the acenaphthene ring system is essentially planar, with a maximum deviation of 0.041 (3) Å. The benzene rings bonded to the the N atoms are essentially parallel, forming a dihedral angle of 0.80 (11)°, and these rings form dihedral angles of 87.49 (9) and 88.25 (10)° with the mean plane of the acenaphthene ring system. The methyl C atoms of three of the isopropyl groups are disordered of two sets of sites of equal occupancy.

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JO - Acta Crystallographica Section E: Structure Reports Online

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