1,3:4,6-Di-O-benzylidene-2,5-O-3,6,9,12-tetraoxatetradecane-l,14-diyl-D-mannitol and the solution state structure of its molecular complex with the benzylammonium cation. A variable-temperature 1H N.M.R. spectroscopic investigation

Steven E. Fuller, Brian E. Mann, J. Fraser Stoddart

Research output: Contribution to journalArticlepeer-review

9 Scopus citations

Abstract

The results of variable-temperature 1H n.m.r. spectroscopic investigations, including both multiple irradiation experiments and qualitative measurements of nuclear Overhauser effects, on D-(2)-PhCH2NH3ClO4 indicate that the conformation (Ha/Hc) in which the phenyl ring in the cation is oriented over one of the 1,3-dioxan rings in D-(2) becomes increasingly preferred in CD2Cl2 solution as the temperature is lowered.

Original languageEnglish (US)
Pages (from-to)1096-1097
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number19
DOIs
StatePublished - 1982

ASJC Scopus subject areas

  • Molecular Medicine

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