1,3:4,6-Di-O-benzylidene-2,5-O-3,6,9,12-tetraoxatetradecane-l,14-diyl-D-mannitol and the solution state structure of its molecular complex with the benzylammonium cation. A variable-temperature 1H N.M.R. spectroscopic investigation

Steven E. Fuller; Brian E. Mann; J. Fraser Stoddart

doi:10.1039/C39820001096

1,3:4,6-Di-O-benzylidene-2,5-O-3,6,9,12-tetraoxatetradecane-l,14-diyl-D-mannitol and the solution state structure of its molecular complex with the benzylammonium cation. A variable-temperature ¹H N.M.R. spectroscopic investigation

Steven E. Fuller, Brian E. Mann, J. Fraser Stoddart

Chemistry

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

The results of variable-temperature ¹H n.m.r. spectroscopic investigations, including both multiple irradiation experiments and qualitative measurements of nuclear Overhauser effects, on D-(2)-PhCH₂NH₃ClO₄ indicate that the conformation (Ha/Hc) in which the phenyl ring in the cation is oriented over one of the 1,3-dioxan rings in D-(2) becomes increasingly preferred in CD₂Cl₂ solution as the temperature is lowered.

Original language	English (US)
Pages (from-to)	1096-1097
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	19
DOIs	https://doi.org/10.1039/C39820001096
State	Published - 1982

ASJC Scopus subject areas

Molecular Medicine

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10.1039/C39820001096

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Fuller, S. E., Mann, B. E., & Stoddart, J. F. (1982). 1,3:4,6-Di-O-benzylidene-2,5-O-3,6,9,12-tetraoxatetradecane-l,14-diyl-D-mannitol and the solution state structure of its molecular complex with the benzylammonium cation. A variable-temperature ¹H N.M.R. spectroscopic investigation. Journal of the Chemical Society, Chemical Communications, (19), 1096-1097. https://doi.org/10.1039/C39820001096

Fuller, Steven E. ; Mann, Brian E. ; Stoddart, J. Fraser. / 1,3:4,6-Di-O-benzylidene-2,5-O-3,6,9,12-tetraoxatetradecane-l,14-diyl-D-mannitol and the solution state structure of its molecular complex with the benzylammonium cation. A variable-temperature ¹H N.M.R. spectroscopic investigation. In: Journal of the Chemical Society, Chemical Communications. 1982 ; No. 19. pp. 1096-1097.

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title = "1,3:4,6-Di-O-benzylidene-2,5-O-3,6,9,12-tetraoxatetradecane-l,14-diyl-D-mannitol and the solution state structure of its molecular complex with the benzylammonium cation. A variable-temperature 1H N.M.R. spectroscopic investigation",

abstract = "The results of variable-temperature 1H n.m.r. spectroscopic investigations, including both multiple irradiation experiments and qualitative measurements of nuclear Overhauser effects, on D-(2)-PhCH2NH3ClO4 indicate that the conformation (Ha/Hc) in which the phenyl ring in the cation is oriented over one of the 1,3-dioxan rings in D-(2) becomes increasingly preferred in CD2Cl2 solution as the temperature is lowered.",

author = "Fuller, {Steven E.} and Mann, {Brian E.} and Stoddart, {J. Fraser}",

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doi = "10.1039/C39820001096",

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journal = "Journal of the Chemical Society, Chemical Communications",

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Fuller, SE, Mann, BE & Stoddart, JF 1982, '1,3:4,6-Di-O-benzylidene-2,5-O-3,6,9,12-tetraoxatetradecane-l,14-diyl-D-mannitol and the solution state structure of its molecular complex with the benzylammonium cation. A variable-temperature ¹H N.M.R. spectroscopic investigation', Journal of the Chemical Society, Chemical Communications, no. 19, pp. 1096-1097. https://doi.org/10.1039/C39820001096

1,3:4,6-Di-O-benzylidene-2,5-O-3,6,9,12-tetraoxatetradecane-l,14-diyl-D-mannitol and the solution state structure of its molecular complex with the benzylammonium cation. A variable-temperature ¹H N.M.R. spectroscopic investigation. / Fuller, Steven E.; Mann, Brian E.; Stoddart, J. Fraser.

In: Journal of the Chemical Society, Chemical Communications, No. 19, 1982, p. 1096-1097.

Research output: Contribution to journal › Article › peer-review

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