TY - JOUR
T1 - 1,3:4,6-Di-O-benzylidene-2,5-O-3,6,9,12-tetraoxatetradecane-l,14-diyl-D-mannitol and the solution state structure of its molecular complex with the benzylammonium cation. A variable-temperature 1H N.M.R. spectroscopic investigation
AU - Fuller, Steven E.
AU - Mann, Brian E.
AU - Stoddart, J. Fraser
PY - 1982
Y1 - 1982
N2 - The results of variable-temperature 1H n.m.r. spectroscopic investigations, including both multiple irradiation experiments and qualitative measurements of nuclear Overhauser effects, on D-(2)-PhCH2NH3ClO4 indicate that the conformation (Ha/Hc) in which the phenyl ring in the cation is oriented over one of the 1,3-dioxan rings in D-(2) becomes increasingly preferred in CD2Cl2 solution as the temperature is lowered.
AB - The results of variable-temperature 1H n.m.r. spectroscopic investigations, including both multiple irradiation experiments and qualitative measurements of nuclear Overhauser effects, on D-(2)-PhCH2NH3ClO4 indicate that the conformation (Ha/Hc) in which the phenyl ring in the cation is oriented over one of the 1,3-dioxan rings in D-(2) becomes increasingly preferred in CD2Cl2 solution as the temperature is lowered.
UR - http://www.scopus.com/inward/record.url?scp=37049113633&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=37049113633&partnerID=8YFLogxK
U2 - 10.1039/C39820001096
DO - 10.1039/C39820001096
M3 - Article
AN - SCOPUS:37049113633
SP - 1096
EP - 1097
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
SN - 0022-4936
IS - 19
ER -