A [2] Catenane Made to Order

Peter R. Ashton; Timothy T. Goodnow; Angel E. Kaifer; Mark V. Reddington; Alexandra M Z Slawin; Neil Spencer; J. Fraser Stoddart; Cristina Vicent; David J. Williams

doi:10.1002/anie.198913961

A [2] Catenane Made to Order

Peter R. Ashton, Timothy T. Goodnow, Angel E. Kaifer, Mark V. Reddington, Alexandra M Z Slawin, Neil Spencer, J. Fraser Stoddart^*, Cristina Vicent, David J. Williams

^*Corresponding author for this work

Chemistry

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348 Scopus citations

Abstract

A template‐controlled, one‐pot reaction afforded the [2]catenane 1 in 70% yield. Compound 1 consists of π‐electron‐rich decaoxa[13.13]paracyclophane (empty circles) and an electron‐deficient macrocycle made up of two paraquat p‐phenylene units (filled circles). Dynamic ¹ H NMR spectroscopy and cyclovoltammetry showed that 1 is highly ordered not only in the solid state but also in solution. (Figure Presented.)

Original language	English (US)
Pages (from-to)	1396-1399
Number of pages	4
Journal	Angewandte Chemie International Edition in English
Volume	28
Issue number	10
DOIs	https://doi.org/10.1002/anie.198913961
State	Published - Oct 1989

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Catalysis
Chemistry(all)

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title = "A [2] Catenane Made to Order",

abstract = "A template‐controlled, one‐pot reaction afforded the [2]catenane 1 in 70% yield. Compound 1 consists of π‐electron‐rich decaoxa[13.13]paracyclophane (empty circles) and an electron‐deficient macrocycle made up of two paraquat p‐phenylene units (filled circles). Dynamic 1 H NMR spectroscopy and cyclovoltammetry showed that 1 is highly ordered not only in the solid state but also in solution. (Figure Presented.)",

author = "Ashton, {Peter R.} and Goodnow, {Timothy T.} and Kaifer, {Angel E.} and Reddington, {Mark V.} and Slawin, {Alexandra M Z} and Neil Spencer and Stoddart, {J. Fraser} and Cristina Vicent and Williams, {David J.}",

year = "1989",

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AU - Ashton, Peter R.

AU - Goodnow, Timothy T.

AU - Kaifer, Angel E.

AU - Reddington, Mark V.

AU - Slawin, Alexandra M Z

AU - Spencer, Neil

AU - Stoddart, J. Fraser

AU - Vicent, Cristina

AU - Williams, David J.

PY - 1989/10

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N2 - A template‐controlled, one‐pot reaction afforded the [2]catenane 1 in 70% yield. Compound 1 consists of π‐electron‐rich decaoxa[13.13]paracyclophane (empty circles) and an electron‐deficient macrocycle made up of two paraquat p‐phenylene units (filled circles). Dynamic 1 H NMR spectroscopy and cyclovoltammetry showed that 1 is highly ordered not only in the solid state but also in solution. (Figure Presented.)

AB - A template‐controlled, one‐pot reaction afforded the [2]catenane 1 in 70% yield. Compound 1 consists of π‐electron‐rich decaoxa[13.13]paracyclophane (empty circles) and an electron‐deficient macrocycle made up of two paraquat p‐phenylene units (filled circles). Dynamic 1 H NMR spectroscopy and cyclovoltammetry showed that 1 is highly ordered not only in the solid state but also in solution. (Figure Presented.)

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ER -

A [2] Catenane Made to Order

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