A Bent vs. Linear Nitrosyl Paradox. Infrared and X-Ray Photoelectron Spectra of CoCl2(NO)L2 and Crystal Structure with L = P(CH3XC6H5)2

Carolyn Pratt Brock, James P. Collman*, Giuliano Dolcetti, Paul H. Farnham, James A. Ibers, J. E. Lester, C. A. Reed

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

79 Scopus citations

Abstract

Infrared, pmr, and X-ray photoelectron spectral data are presented to substantiate the existence of conformational isomers of the nitrosyl complexes CoCl2(NO)L2. The first isomer A has trigonal-bipyramidal geometry with a linear nitrosyl (NO+) while the second isomer B is believed to have square-pyramidal geometry with a bent nitrosyl (NO+) at the apex. A low-temperature crystalline form of CoCl2(NO)(P(CH3)(C6H5)2)2 containing almost solely isomer A was found to transform partially to B by grinding in preparation for a Nujol mull. Nitrogen Is electron binding energies suggest an unexpectedly high preference for isomer B at the surface of most solid samples. The crystal and molecular structures of the room-temperature form of CoCl2(NO)(P(CH3)(C6H5)2)2 have been determined from three-dimensional X-ray data collected at room temperature by counter methods. The material crystallizes with 8 molecules in space group C2h6-C2/c of the monoclinic system in a cell of dimensions a= 16.970 (14), b = 17.035 (9), c= 18.735 (8) Å, and ²= 108.00 (2)°. The calculated and observed densities are 1.445 and 1.44(2) g cm-3, respectively. The structure has been solved and refined by conventional mean. The final R factor (on F) for the 2428 unique reflections having Fo2> 3σ(Fo2) is 0.046. The resultant structure is of isomer A, a somewhat distorted trigonal bipyramid, and there is no evidence for the coexistence of isomer B in the crystal used in the X-ray analysis.

Original languageEnglish (US)
Pages (from-to)1304-1313
Number of pages10
JournalInorganic chemistry
Volume12
Issue number6
DOIs
StatePublished - Jun 1 1973

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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