A canted antiferromagnetic ordered phase of cyanido-bridged MnIII2ReIVsingle-chain magnets

Indrani Bhowmick; Elizabeth A. Hillard; Pierre Dechambenoit; Claude Coulon; T. David Harris; Rodolphe Clérac

doi:10.1039/c2cc34066f

A canted antiferromagnetic ordered phase of cyanido-bridged Mn^III₂Re^IVsingle-chain magnets

Indrani Bhowmick, Elizabeth A. Hillard, Pierre Dechambenoit, Claude Coulon, T. David Harris, Rodolphe Clérac^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

55 Scopus citations

Abstract

A new cyanido-bridged Re^IV–Mn^III heterometallic 1D system, [Mn^III(5-Me-saltmen)]₂[Re^IVCl₄(CN)₂]·3CH₃CN (1), was designed and structurally characterized. Interchain interactions stabilize a canted antiferromagnetic ordered state below 6.2 K that does not prevent slow relaxation of the magnetization reminiscent of the single-chain magnet properties of the individual chains.

Original language	English (US)
Pages (from-to)	9717-9719
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	78
DOIs	https://doi.org/10.1039/c2cc34066f
State	Published - Sep 5 2012

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "A canted antiferromagnetic ordered phase of cyanido-bridged MnIII2ReIVsingle-chain magnets",

abstract = "A new cyanido-bridged ReIV–MnIII heterometallic 1D system, [MnIII(5-Me-saltmen)]2[ReIVCl4(CN)2]·3CH3CN (1), was designed and structurally characterized. Interchain interactions stabilize a canted antiferromagnetic ordered state below 6.2 K that does not prevent slow relaxation of the magnetization reminiscent of the single-chain magnet properties of the individual chains.",

author = "Indrani Bhowmick and Hillard, {Elizabeth A.} and Pierre Dechambenoit and Claude Coulon and Harris, {T. David} and Rodolphe Cl{\'e}rac",

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T1 - A canted antiferromagnetic ordered phase of cyanido-bridged MnIII2ReIVsingle-chain magnets

AU - Bhowmick, Indrani

AU - Hillard, Elizabeth A.

AU - Dechambenoit, Pierre

AU - Coulon, Claude

AU - Harris, T. David

AU - Clérac, Rodolphe

PY - 2012/9/5

Y1 - 2012/9/5

N2 - A new cyanido-bridged ReIV–MnIII heterometallic 1D system, [MnIII(5-Me-saltmen)]2[ReIVCl4(CN)2]·3CH3CN (1), was designed and structurally characterized. Interchain interactions stabilize a canted antiferromagnetic ordered state below 6.2 K that does not prevent slow relaxation of the magnetization reminiscent of the single-chain magnet properties of the individual chains.

AB - A new cyanido-bridged ReIV–MnIII heterometallic 1D system, [MnIII(5-Me-saltmen)]2[ReIVCl4(CN)2]·3CH3CN (1), was designed and structurally characterized. Interchain interactions stabilize a canted antiferromagnetic ordered state below 6.2 K that does not prevent slow relaxation of the magnetization reminiscent of the single-chain magnet properties of the individual chains.

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JO - Chemical Communications

JF - Chemical Communications

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ER -

A canted antiferromagnetic ordered phase of cyanido-bridged Mn^III₂Re^IVsingle-chain magnets

Abstract

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