Abstract
Through the use of the tetratopic ligand 1,2,4,5-tetrakis(4-carboxyphenyl) benzene as a key building block, a permanently microporous metal-organic framework with Lewis acidic (porphyrin)Zn struts, ZnPO-MOF, can be made in high yields. ZnPO-MOF can efficiently catalyze acyl-transfer reactions primarily by preconcentrating the substrates within its pores, in stark contrast to analogous supramolecular systems.
Original language | English (US) |
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Pages (from-to) | 4204-4205 |
Number of pages | 2 |
Journal | Journal of the American Chemical Society |
Volume | 131 |
Issue number | 12 |
DOIs | |
State | Published - Apr 1 2009 |
ASJC Scopus subject areas
- General Chemistry
- Biochemistry
- Catalysis
- Colloid and Surface Chemistry
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CCDC 739150: Experimental Crystal Structure Determination
Shultz, A. M. (Contributor), Farha, O. K. (Contributor), Hupp, J. T. (Contributor) & Nguyen, S. T. (Contributor), Cambridge Crystallographic Data Centre, 2010
DOI: 10.5517/ccst4k8, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccst4k8&sid=DataCite
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