A catalytically active vanadyl(catecholate)-decorated metal organic framework via post-synthesis modifications

Huong Giang T. Nguyen; Mitchell H. Weston; Omar K. Farha; Joseph T. Hupp; Sonbinh T. Nguyen

doi:10.1039/c2ce06666a

A catalytically active vanadyl(catecholate)-decorated metal organic framework via post-synthesis modifications

Huong Giang T. Nguyen, Mitchell H. Weston, Omar K. Farha^*, Joseph T. Hupp, Sonbinh T. Nguyen

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

52 Scopus citations

Abstract

A vanadyl(monocatecholate)-decorated metal-organic framework was synthesized using two sequential post-synthesis modifications. This material is catalytically active for the oxidation of organo-sulfide. In contrast to the homogeneous control catalyst, it can be tuned to be selective for the sulfoxide product using tert-butyl hydroperoxide as oxidant.

Original language	English (US)
Pages (from-to)	4115-4118
Number of pages	4
Journal	CrystEngComm
Volume	14
Issue number	12
DOIs	https://doi.org/10.1039/c2ce06666a
State	Published - Jun 21 2012

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

Access to Document

10.1039/c2ce06666a

Cite this

@article{5838ef0e66564c84ab216f59bf59db96,

title = "A catalytically active vanadyl(catecholate)-decorated metal organic framework via post-synthesis modifications",

abstract = "A vanadyl(monocatecholate)-decorated metal-organic framework was synthesized using two sequential post-synthesis modifications. This material is catalytically active for the oxidation of organo-sulfide. In contrast to the homogeneous control catalyst, it can be tuned to be selective for the sulfoxide product using tert-butyl hydroperoxide as oxidant.",

author = "Nguyen, {Huong Giang T.} and Weston, {Mitchell H.} and Farha, {Omar K.} and Hupp, {Joseph T.} and Nguyen, {Sonbinh T.}",

year = "2012",

month = jun,

day = "21",

doi = "10.1039/c2ce06666a",

language = "English (US)",

volume = "14",

pages = "4115--4118",

journal = "CrystEngComm",

issn = "1466-8033",

publisher = "Royal Society of Chemistry",

number = "12",

}

TY - JOUR

T1 - A catalytically active vanadyl(catecholate)-decorated metal organic framework via post-synthesis modifications

AU - Nguyen, Huong Giang T.

AU - Weston, Mitchell H.

AU - Farha, Omar K.

AU - Hupp, Joseph T.

AU - Nguyen, Sonbinh T.

PY - 2012/6/21

Y1 - 2012/6/21

N2 - A vanadyl(monocatecholate)-decorated metal-organic framework was synthesized using two sequential post-synthesis modifications. This material is catalytically active for the oxidation of organo-sulfide. In contrast to the homogeneous control catalyst, it can be tuned to be selective for the sulfoxide product using tert-butyl hydroperoxide as oxidant.

AB - A vanadyl(monocatecholate)-decorated metal-organic framework was synthesized using two sequential post-synthesis modifications. This material is catalytically active for the oxidation of organo-sulfide. In contrast to the homogeneous control catalyst, it can be tuned to be selective for the sulfoxide product using tert-butyl hydroperoxide as oxidant.

UR - http://www.scopus.com/inward/record.url?scp=84862296343&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84862296343&partnerID=8YFLogxK

U2 - 10.1039/c2ce06666a

DO - 10.1039/c2ce06666a

M3 - Article

AN - SCOPUS:84862296343

SN - 1466-8033

VL - 14

SP - 4115

EP - 4118

JO - CrystEngComm

JF - CrystEngComm

IS - 12

ER -

A catalytically active vanadyl(catecholate)-decorated metal organic framework via post-synthesis modifications

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this