A cobalt-germanium bond: the structure of Co[Ge(C6H5)3](CO)3[P(C6H5)3]

Judith K. Stalick; James A. Ibers

doi:10.1016/S0022-328X(00)83094-6

A cobalt-germanium bond: the structure of Co[Ge(C₆H₅)₃](CO)₃[P(C₆H₅)₃]

Judith K. Stalick^*, James A. Ibers

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The structure of Co[Ge(C₆H₅)₃](CO)₃[P(C₆H₅)₃] has been determined from X-ray data collected by counter methods. The material crystallizes with eight molecules in space group C⁶_2h = 12/a in a cell of dimensions a = 18.703(6), b = 15.469(6), c = 24.013(8) Å, β = 105° 42(1)′. The final conventional R factor for the 1345 reflections above background is 0.092. The coordination about Co is that of a trigonal bipyramid, with equatorial carbonyl groups and partially disordered Ge(C₆H₅)₃ and P(C₆H₅)₃ axial groups. The CoGe bond length of 2.34(2) Å is consistent with a degree of CoGe multiple bonding.

Original language	English (US)
Pages (from-to)	203-211
Number of pages	9
Journal	Journal of Organometallic Chemistry
Volume	22
Issue number	1
DOIs	https://doi.org/10.1016/S0022-328X(00)83094-6
State	Published - Mar 1970

Funding

We are grateful to Professor M. D. Curtis for generously supplying the crystals. We wish to thank the National Science Foundation for its support of this work. J.K.S. gratefully acknowledges the National Science Foundation for support through a predoctoral fellowship.

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0022-328X(00)83094-6

Cite this

@article{158ca66ed1d94a88965569dfcc74adbe,

title = "A cobalt-germanium bond: the structure of Co[Ge(C6H5)3](CO)3[P(C6H5)3]",

abstract = "The structure of Co[Ge(C6H5)3](CO)3[P(C6H5)3] has been determined from X-ray data collected by counter methods. The material crystallizes with eight molecules in space group C62h = 12/a in a cell of dimensions a = 18.703(6), b = 15.469(6), c = 24.013(8) {\AA}, β = 105° 42(1)′. The final conventional R factor for the 1345 reflections above background is 0.092. The coordination about Co is that of a trigonal bipyramid, with equatorial carbonyl groups and partially disordered Ge(C6H5)3 and P(C6H5)3 axial groups. The CoGe bond length of 2.34(2) {\AA} is consistent with a degree of CoGe multiple bonding.",

author = "Stalick, \{Judith K.\} and Ibers, \{James A.\}",

note = "Funding Information: We are grateful to Professor M. D. Curtis for generously supplying the crystals. We wish to thank the National Science Foundation for its support of this work. J.K.S. gratefully acknowledges the National Science Foundation for support through a predoctoral fellowship.",

year = "1970",

month = mar,

doi = "10.1016/S0022-328X(00)83094-6",

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T1 - A cobalt-germanium bond

T2 - the structure of Co[Ge(C6H5)3](CO)3[P(C6H5)3]

AU - Stalick, Judith K.

AU - Ibers, James A.

N1 - Funding Information: We are grateful to Professor M. D. Curtis for generously supplying the crystals. We wish to thank the National Science Foundation for its support of this work. J.K.S. gratefully acknowledges the National Science Foundation for support through a predoctoral fellowship.

PY - 1970/3

Y1 - 1970/3

N2 - The structure of Co[Ge(C6H5)3](CO)3[P(C6H5)3] has been determined from X-ray data collected by counter methods. The material crystallizes with eight molecules in space group C62h = 12/a in a cell of dimensions a = 18.703(6), b = 15.469(6), c = 24.013(8) Å, β = 105° 42(1)′. The final conventional R factor for the 1345 reflections above background is 0.092. The coordination about Co is that of a trigonal bipyramid, with equatorial carbonyl groups and partially disordered Ge(C6H5)3 and P(C6H5)3 axial groups. The CoGe bond length of 2.34(2) Å is consistent with a degree of CoGe multiple bonding.

AB - The structure of Co[Ge(C6H5)3](CO)3[P(C6H5)3] has been determined from X-ray data collected by counter methods. The material crystallizes with eight molecules in space group C62h = 12/a in a cell of dimensions a = 18.703(6), b = 15.469(6), c = 24.013(8) Å, β = 105° 42(1)′. The final conventional R factor for the 1345 reflections above background is 0.092. The coordination about Co is that of a trigonal bipyramid, with equatorial carbonyl groups and partially disordered Ge(C6H5)3 and P(C6H5)3 axial groups. The CoGe bond length of 2.34(2) Å is consistent with a degree of CoGe multiple bonding.

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