TY - JOUR
T1 - A cobalt-germanium bond
T2 - the structure of Co[Ge(C6H5)3](CO)3[P(C6H5)3]
AU - Stalick, Judith K.
AU - Ibers, James A.
N1 - Funding Information:
We are grateful to Professor M. D. Curtis for generously supplying the crystals. We wish to thank the National Science Foundation for its support of this work. J.K.S. gratefully acknowledges the National Science Foundation for support through a predoctoral fellowship.
PY - 1970/3
Y1 - 1970/3
N2 - The structure of Co[Ge(C6H5)3](CO)3[P(C6H5)3] has been determined from X-ray data collected by counter methods. The material crystallizes with eight molecules in space group C62h = 12/a in a cell of dimensions a = 18.703(6), b = 15.469(6), c = 24.013(8) Å, β = 105° 42(1)′. The final conventional R factor for the 1345 reflections above background is 0.092. The coordination about Co is that of a trigonal bipyramid, with equatorial carbonyl groups and partially disordered Ge(C6H5)3 and P(C6H5)3 axial groups. The CoGe bond length of 2.34(2) Å is consistent with a degree of CoGe multiple bonding.
AB - The structure of Co[Ge(C6H5)3](CO)3[P(C6H5)3] has been determined from X-ray data collected by counter methods. The material crystallizes with eight molecules in space group C62h = 12/a in a cell of dimensions a = 18.703(6), b = 15.469(6), c = 24.013(8) Å, β = 105° 42(1)′. The final conventional R factor for the 1345 reflections above background is 0.092. The coordination about Co is that of a trigonal bipyramid, with equatorial carbonyl groups and partially disordered Ge(C6H5)3 and P(C6H5)3 axial groups. The CoGe bond length of 2.34(2) Å is consistent with a degree of CoGe multiple bonding.
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U2 - 10.1016/S0022-328X(00)83094-6
DO - 10.1016/S0022-328X(00)83094-6
M3 - Article
AN - SCOPUS:49849110048
VL - 22
SP - 203
EP - 211
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
SN - 0022-328X
IS - 1
ER -