A comparison between the solid state structures and solution behaviour of molecular complexes formed between primary alkylammonium salts and chiral crown ethers incorporating 1,2:4,6-diacetals of D-mannitol

Steven E. Fuller, J. Fraser Stoddart, David J. Williams

Research output: Contribution to journalArticlepeer-review

4 Scopus citations

Abstract

The results of an X-ray crystallographic study of D-(1)-Me2CHNH3ClO4 and D-(2)-PhCH2NH3CIO4 reveal conformational features and a hydrogen bonding pattern in the 1:1 complexes which may be correlated with the complexaton behaviour of the 20-crown-6 derivatives D-(1), D-(2), and (3) in solution towards a range of cationic guest species.

Original languageEnglish (US)
Pages (from-to)1093-1096
Number of pages4
JournalJournal of the Chemical Society D: Chemical Communications
Issue number19
DOIs
StatePublished - 1982

ASJC Scopus subject areas

  • Molecular Medicine

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