TY - JOUR
T1 - A comparison of the receptor stereochemistry in [Pt(bipy)(NH 3)2·dinaphtho-30-crown-10][PF6] 2 and [Diquat·dinaphtho-30-crown-10][PF6] 2 (bipy = 2,2′-bipyridine)
AU - Allwood, Billy L.
AU - Colquhoun, Howard M.
AU - Doughty, Simon M.
AU - Kohnke, Franz H.
AU - Slawin, Alexandra M Z
AU - Stoddart, J. Fraser
AU - Williams, David J.
AU - Zarzycki, Ryszard
PY - 1987
Y1 - 1987
N2 - X-Ray crystallography and 1H n.m.r. spectroscopy have revealed dramatic differences in the binding of [Pt(bipy)(NH3) 2]2+ and [Diquat]2+ dications by dinaphtho-30-crown-10 (DN30C10) with the platinum complex adopting a slewed position, apparently in order to maximise overlap between the π-arene systems in the receptor and in the complex, whereas the Diquat dication adopts a symmetrical position more consistent with maximisation of Coulombic interactions.
AB - X-Ray crystallography and 1H n.m.r. spectroscopy have revealed dramatic differences in the binding of [Pt(bipy)(NH3) 2]2+ and [Diquat]2+ dications by dinaphtho-30-crown-10 (DN30C10) with the platinum complex adopting a slewed position, apparently in order to maximise overlap between the π-arene systems in the receptor and in the complex, whereas the Diquat dication adopts a symmetrical position more consistent with maximisation of Coulombic interactions.
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U2 - 10.1039/C39870001054
DO - 10.1039/C39870001054
M3 - Article
AN - SCOPUS:37049080118
SN - 0022-4936
SP - 1054
EP - 1058
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 14
ER -