Abstract
Epoxide and CO2 coupling reactions catalyzed by (salen)CrIIICl have been modeled computationally to contrast a monometallic vs. a bimetallic mechanism. A low-energy CO2 insertion step into the metal-alkoxide bond was located.
Original language | English (US) |
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Pages (from-to) | 2676-2678 |
Number of pages | 3 |
Journal | Chemical Communications |
Volume | 50 |
Issue number | 20 |
DOIs | |
State | Published - Feb 11 2014 |
ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry