A Continuous Test Data Method to Determine a Reference Curve and Shift Rate for Isothermal Physical Aging

R. D. Bradshaw, L. C. Brinson*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

24 Scopus citations

Abstract

The mechanical response of a material undergoing isothermal physical aging is governed by a reference curve (typically time-dependent modulus or compliance) and a shift rate (which describes the rate of aging). In the standard analysis approach, these parameters are determined from a series of load/unload creep or relaxation tests, in which only the load portion data is used for property evaluation. In this paper, a new continuous test data (CTD) method is presented to determine these parameters using both the load and unload data from such a test series. This is accomplished by employing effective time theory to predict the full load/unload data set, with the reference curve and shift rate obtained as those which best fit the experimental data. It is demonstrated that the reference curve obtained via the standard approach is not capable of predicting the full load/unload data set, while the CTD method using a Prony series fits this same data very well. Several concerns regarding the CTD method are addressed, including the differences in the CTD and standard method shift rate, the effect of vertical shifting or material non-linearity on the results, and application of the method to other loading scenarios. Results are presented for long-term and variable stress tests. The data used in the study was obtained from polyimide resin and polyimide/carbon fiber composite specimens at several temperatures below Tg.

Original languageEnglish (US)
Pages (from-to)211-235
Number of pages25
JournalPolymer Engineering and Science
Volume39
Issue number2
DOIs
StatePublished - Jan 1 1999

ASJC Scopus subject areas

  • Chemistry(all)
  • Polymers and Plastics
  • Materials Chemistry

Fingerprint Dive into the research topics of 'A Continuous Test Data Method to Determine a Reference Curve and Shift Rate for Isothermal Physical Aging'. Together they form a unique fingerprint.

Cite this