TY - GEN
T1 - A correlative five-dimensional study of phase separation at the subnano- to nanoscale of nickel-aluminum alloys
T2 - International Conference on Solid-Solid Phase Transformations in Inorganic Materials 2015, PTM 2015
AU - Seidman, David N.
AU - Plotnikov, Elizaveta Y.
AU - Mao, Zugang
AU - Noebe, Ronald D.
N1 - Funding Information:
This research was supported by the National Science Foundation (NSF), Division of Materials Research (DMR) grant number 1207539, Prof. G. Shiflet, grant monitor. Atom-probe tomography was performed at the Northwestern University Center for Atom-Probe Tomography (NUCAPT), whose LEAP tomograph was purchased and upgraded with funding from NSF-MRI (DMR-0420532) and ONR-DURIP (N00014-0400798, N00014-0610539, N00014-0910781). Instrumentation at NUCAPT was further upgraded by the Initiative for Sustainability and Energy at Northwestern (ISEN). NUCAPT is a Shared Facility of the Materials Research Center of Northwestern University, partially supported by the National Science Foundation's MRSEC program (DMR-1121262). The authors thank Dr. N. Dupin for generous access to her Thermo-Calc data for the partial Ni-Al phase diagram. We also thank Dr. G. Martin and Prof. P. W. Voorhees for stimulating and valuable discussions.
PY - 2015
Y1 - 2015
N2 - The temporal evolution of ordered γ'(L12 structure)-precipitates precipitating in a disordered γ(f.c.c. structure)-matrix is studied for Ni-12.5 Al and Ni-13.4 Al at.% alloys aged at 773, 798, 823, or 873 K for times ranging from 0.08 to 10,287 h in a detailed and comprehensive study utilizing three-dimensional atom-probe tomography (3-D APT), transmission electron microscopy (TEM) and monovacancy-mediated lattice-kinetic Monte Carlo (LKMC1) simulations. [1] The 3-D APT results are compared in detail to LKMC1 simulations, which include monovacancy-solute binding energies through 4th nearest-neighbor distances, for the same mean compositions and aging temperatures. The temporal evolution of the measured values of the mean radius, number density, aluminum supersaturation, and volume fraction of the γ'(L12)-precipitates are compared to the predictions of a modified version of the Lifshitz-Slyozov [2] and Wagner [3] coarsening model due to Calderon, Voorhees, Murray and Kostorz [4], which takes into account the thermodynamics of the γ(fc.c.)-matrix. The resulting experimental rate constants are used to calculate the Gibbs interfacial free-energies between the γ(f.c.c)- and γ'(L12)-phases using data from two thermodynamic databases, and its value is compared to archival values dating from 1966. The diffusion coefficient for coarsening is then calculated from the same rate constants and is compared to all extant archival diffusivities, not determined from coarsening experiments, and is demonstrated to be the interdiffusivity, D∼, of Ni and Al at the four aging temperatures. The monovacancy-mediated LKMC1 simulation results are found to be in good agreement with 3-D APT data for all the quantities determined by 3-D APT. Furthermore, it is demonstrated that the compositional interfacial width, for the (100) interface, between the γ(f.c.c)- and γ'(L12)-phases, decreases continuously with increasing aging time and mean radius for the 3-D APT results and the monovacancy-mediated LKMC1 simulations [5], in disagreement with the ansatz that is intrinsic to the trans-interface diffusioncontrolled coarsening model, which predicts the opposite trend for binary Ni-Al alloys [6].
AB - The temporal evolution of ordered γ'(L12 structure)-precipitates precipitating in a disordered γ(f.c.c. structure)-matrix is studied for Ni-12.5 Al and Ni-13.4 Al at.% alloys aged at 773, 798, 823, or 873 K for times ranging from 0.08 to 10,287 h in a detailed and comprehensive study utilizing three-dimensional atom-probe tomography (3-D APT), transmission electron microscopy (TEM) and monovacancy-mediated lattice-kinetic Monte Carlo (LKMC1) simulations. [1] The 3-D APT results are compared in detail to LKMC1 simulations, which include monovacancy-solute binding energies through 4th nearest-neighbor distances, for the same mean compositions and aging temperatures. The temporal evolution of the measured values of the mean radius, number density, aluminum supersaturation, and volume fraction of the γ'(L12)-precipitates are compared to the predictions of a modified version of the Lifshitz-Slyozov [2] and Wagner [3] coarsening model due to Calderon, Voorhees, Murray and Kostorz [4], which takes into account the thermodynamics of the γ(fc.c.)-matrix. The resulting experimental rate constants are used to calculate the Gibbs interfacial free-energies between the γ(f.c.c)- and γ'(L12)-phases using data from two thermodynamic databases, and its value is compared to archival values dating from 1966. The diffusion coefficient for coarsening is then calculated from the same rate constants and is compared to all extant archival diffusivities, not determined from coarsening experiments, and is demonstrated to be the interdiffusivity, D∼, of Ni and Al at the four aging temperatures. The monovacancy-mediated LKMC1 simulation results are found to be in good agreement with 3-D APT data for all the quantities determined by 3-D APT. Furthermore, it is demonstrated that the compositional interfacial width, for the (100) interface, between the γ(f.c.c)- and γ'(L12)-phases, decreases continuously with increasing aging time and mean radius for the 3-D APT results and the monovacancy-mediated LKMC1 simulations [5], in disagreement with the ansatz that is intrinsic to the trans-interface diffusioncontrolled coarsening model, which predicts the opposite trend for binary Ni-Al alloys [6].
KW - Atom-probe tomography
KW - Microhardness measurements
KW - Nickel-aluminum alloys
KW - Phase separation
KW - Temporal evolution
KW - Transmission electron microscopy
KW - Vacancy-mediated lattice-kinetics monte carlo simulations
UR - http://www.scopus.com/inward/record.url?scp=84962712422&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84962712422&partnerID=8YFLogxK
M3 - Conference contribution
AN - SCOPUS:84962712422
T3 - PTM 2015 - Proceedings of the International Conference on Solid-Solid Phase Transformations in Inorganic Materials 2015
SP - 143
EP - 144
BT - PTM 2015 - Proceedings of the International Conference on Solid-Solid Phase Transformations in Inorganic Materials 2015
A2 - Chen, Long-Qing
A2 - Militzer, Matthias
A2 - Botton, Gianluigi
A2 - Howe, James
A2 - Sinclair, Chadwick
A2 - Zurob, Hatem
PB - International Conference on Solid-Solid Phase Transformations in Inorganic Materials 2015
Y2 - 28 June 2015 through 3 July 2015
ER -