A crown-linked donor-acceptor assembly containing ReI(diimine)(CO)3Cl and nitrobenzene components

Michelle Absi; Charlotte L. Stern; Dong I. Yoon; Joseph T. Hupp

doi:10.1107/S010827019700036X

A crown-linked donor-acceptor assembly containing Re^I(diimine)(CO)₃Cl and nitrobenzene components

Michelle Absi^*, Charlotte L. Stern, Dong I. Yoon, Joseph T. Hupp

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

The structure of the title assembly, tricarbonylchloro-[16-nitro-3,6,9,12,20,23,26,29-octaoxa-34,37-diazatetra- cyclo[34.3.1.1^14,18.1 ^31,35]dotetraconta-1(39),14,16,18(41),-31, 33, 35(42), 36(40), 37-nonaene-2, 13, 19, 30-tetrone]-rhenium(I), [ReCl(C₃₂H₃₃N₃O₁₄)(CO)₃], has been determined via a single-crystal diffraction study. The rhenium ion is octahedrally coordinated. The bidentate bipyridine/crown ether/nitrobenzene assembly is folded such that the pyridyl rings and nitrobenzene moiety are almost coplanar.

Original language	English (US)
Pages (from-to)	1054-1055
Number of pages	2
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	53
Issue number	8
DOIs	https://doi.org/10.1107/S010827019700036X
State	Published - Aug 15 1997

ASJC Scopus subject areas

Biochemistry, Genetics and Molecular Biology(all)

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10.1107/S010827019700036X

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@article{b1a3e74efbb94d92b4437f9bf9cbec07,

title = "A crown-linked donor-acceptor assembly containing ReI(diimine)(CO)3Cl and nitrobenzene components",

abstract = "The structure of the title assembly, tricarbonylchloro-[16-nitro-3,6,9,12,20,23,26,29-octaoxa-34,37-diazatetra- cyclo[34.3.1.114,18.1 31,35]dotetraconta-1(39),14,16,18(41),-31, 33, 35(42), 36(40), 37-nonaene-2, 13, 19, 30-tetrone]-rhenium(I), [ReCl(C32H33N3O14)(CO)3], has been determined via a single-crystal diffraction study. The rhenium ion is octahedrally coordinated. The bidentate bipyridine/crown ether/nitrobenzene assembly is folded such that the pyridyl rings and nitrobenzene moiety are almost coplanar.",

author = "Michelle Absi and Stern, {Charlotte L.} and Yoon, {Dong I.} and Hupp, {Joseph T.}",

year = "1997",

month = aug,

day = "15",

doi = "10.1107/S010827019700036X",

language = "English (US)",

volume = "53",

pages = "1054--1055",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "8",

}

TY - JOUR

T1 - A crown-linked donor-acceptor assembly containing ReI(diimine)(CO)3Cl and nitrobenzene components

AU - Absi, Michelle

AU - Stern, Charlotte L.

AU - Yoon, Dong I.

AU - Hupp, Joseph T.

PY - 1997/8/15

Y1 - 1997/8/15

N2 - The structure of the title assembly, tricarbonylchloro-[16-nitro-3,6,9,12,20,23,26,29-octaoxa-34,37-diazatetra- cyclo[34.3.1.114,18.1 31,35]dotetraconta-1(39),14,16,18(41),-31, 33, 35(42), 36(40), 37-nonaene-2, 13, 19, 30-tetrone]-rhenium(I), [ReCl(C32H33N3O14)(CO)3], has been determined via a single-crystal diffraction study. The rhenium ion is octahedrally coordinated. The bidentate bipyridine/crown ether/nitrobenzene assembly is folded such that the pyridyl rings and nitrobenzene moiety are almost coplanar.

AB - The structure of the title assembly, tricarbonylchloro-[16-nitro-3,6,9,12,20,23,26,29-octaoxa-34,37-diazatetra- cyclo[34.3.1.114,18.1 31,35]dotetraconta-1(39),14,16,18(41),-31, 33, 35(42), 36(40), 37-nonaene-2, 13, 19, 30-tetrone]-rhenium(I), [ReCl(C32H33N3O14)(CO)3], has been determined via a single-crystal diffraction study. The rhenium ion is octahedrally coordinated. The bidentate bipyridine/crown ether/nitrobenzene assembly is folded such that the pyridyl rings and nitrobenzene moiety are almost coplanar.

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DO - 10.1107/S010827019700036X

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SN - 0108-2701

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JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

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A crown-linked donor-acceptor assembly containing Re^I(diimine)(CO)₃Cl and nitrobenzene components

Abstract

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CCDC 128935: Experimental Crystal Structure Determination

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A crown-linked donor-acceptor assembly containing ReI(diimine)(CO)3Cl and nitrobenzene components

Abstract

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CCDC 128935: Experimental Crystal Structure Determination

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A crown-linked donor-acceptor assembly containing Re^I(diimine)(CO)₃Cl and nitrobenzene components