A family of [Ni8] cages templated by μ6-peroxide from dioxygen activation

Alexandros Perivolaris; Constantinos C. Stoumpos; Jolanta Karpinska; Alan G. Ryder; Jamie M. Frost; Kevin Mason; Alessandro Prescimone; Alexandra M Z Slawin; Vadim G. Kessler; Jennifer S. Mathieson; Leroy Cronin; Euan K. Brechin; Giannis S. Papaefstathiou

doi:10.1039/c4qi00048j

A family of [Ni₈] cages templated by μ₆-peroxide from dioxygen activation

Alexandros Perivolaris, Constantinos C. Stoumpos, Jolanta Karpinska, Alan G. Ryder, Jamie M. Frost, Kevin Mason, Alessandro Prescimone, Alexandra M Z Slawin, Vadim G. Kessler, Jennifer S. Mathieson, Leroy Cronin, Euan K. Brechin^*, Giannis S. Papaefstathiou

^*Corresponding author for this work

Chemistry

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5 Scopus citations

Abstract

A family of exceptionally thermally stable [Ni₈] cages is reported, each being templated by a rare η³:η³:μ₆-O₂ ^2- species produced by dioxygen activation, where the reducing agent for the O₂ reduction appears to be the ligand used in the reaction mixtures, which was found within the nickel cages in its oxidized form.

Original language	English (US)
Pages (from-to)	487-494
Number of pages	8
Journal	Inorganic Chemistry Frontiers
Volume	1
Issue number	6
DOIs	https://doi.org/10.1039/c4qi00048j
State	Published - Jun 2014

ASJC Scopus subject areas

Inorganic Chemistry

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Perivolaris, A., Stoumpos, C. C., Karpinska, J., Ryder, A. G., Frost, J. M., Mason, K., Prescimone, A., Slawin, A. M. Z., Kessler, V. G., Mathieson, J. S., Cronin, L., Brechin, E. K., & Papaefstathiou, G. S. (2014). A family of [Ni₈] cages templated by μ₆-peroxide from dioxygen activation. Inorganic Chemistry Frontiers, 1(6), 487-494. https://doi.org/10.1039/c4qi00048j

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title = "A family of [Ni8] cages templated by μ6-peroxide from dioxygen activation",

abstract = "A family of exceptionally thermally stable [Ni8] cages is reported, each being templated by a rare η3:η3:μ6-O2 2- species produced by dioxygen activation, where the reducing agent for the O2 reduction appears to be the ligand used in the reaction mixtures, which was found within the nickel cages in its oxidized form.",

author = "Alexandros Perivolaris and Stoumpos, {Constantinos C.} and Jolanta Karpinska and Ryder, {Alan G.} and Frost, {Jamie M.} and Kevin Mason and Alessandro Prescimone and Slawin, {Alexandra M Z} and Kessler, {Vadim G.} and Mathieson, {Jennifer S.} and Leroy Cronin and Brechin, {Euan K.} and Papaefstathiou, {Giannis S.}",

note = "Publisher Copyright: This journal is {\textcopyright} the Partner Organisations 2014.",

year = "2014",

month = jun,

doi = "10.1039/c4qi00048j",

language = "English (US)",

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AU - Perivolaris, Alexandros

AU - Stoumpos, Constantinos C.

AU - Karpinska, Jolanta

AU - Ryder, Alan G.

AU - Frost, Jamie M.

AU - Mason, Kevin

AU - Prescimone, Alessandro

AU - Slawin, Alexandra M Z

AU - Kessler, Vadim G.

AU - Mathieson, Jennifer S.

AU - Cronin, Leroy

AU - Brechin, Euan K.

AU - Papaefstathiou, Giannis S.

PY - 2014/6

Y1 - 2014/6

N2 - A family of exceptionally thermally stable [Ni8] cages is reported, each being templated by a rare η3:η3:μ6-O2 2- species produced by dioxygen activation, where the reducing agent for the O2 reduction appears to be the ligand used in the reaction mixtures, which was found within the nickel cages in its oxidized form.

AB - A family of exceptionally thermally stable [Ni8] cages is reported, each being templated by a rare η3:η3:μ6-O2 2- species produced by dioxygen activation, where the reducing agent for the O2 reduction appears to be the ligand used in the reaction mixtures, which was found within the nickel cages in its oxidized form.

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JO - Inorganic Chemistry Frontiers

JF - Inorganic Chemistry Frontiers

IS - 6

ER -

A family of [Ni₈] cages templated by μ₆-peroxide from dioxygen activation

Abstract

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