A Flexible Metal-Organic Framework with 4-Connected Zr
                        6
                         Nodes

Yuanyuan Zhang; Xuan Zhang; Jiafei Lyu; Ken Ichi Otake; Xingjie Wang; Louis R. Redfern; Christos D. Malliakas; Zhanyong Li; Timur Islamoglu; Bo Wang; Omar K. Farha

doi:10.1021/jacs.8b06789

A Flexible Metal-Organic Framework with 4-Connected Zr ₆ Nodes

Yuanyuan Zhang, Xuan Zhang, Jiafei Lyu, Ken Ichi Otake, Xingjie Wang, Louis R. Redfern, Christos D. Malliakas, Zhanyong Li, Timur Islamoglu, Bo Wang, Omar K. Farha^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

83 Scopus citations

Abstract

Zr-based metal-organic frameworks (MOFs) have been known for their excellent stability; however, due to the high connectivity of the Zr ₆ nodes, it is challenging to introduce flexibility into Zr-MOFs. Here we present a flexible Zr-MOF named NU-1400 comprising 4-connected Zr ₆ nodes and tetratopic linkers. It exhibits guest-dependent structural flexibility with up to 48% contraction in the unit cell volume as evidenced by single-crystal X-ray diffraction studies. The expanded or contracted conformations of NU-1400 showed drastically different reactivity toward the hydrolysis of a nerve agent simulant owing to the size-selective effect toward the reactant.

Original language	English (US)
Pages (from-to)	11179-11183
Number of pages	5
Journal	Journal of the American Chemical Society
Volume	140
Issue number	36
DOIs	https://doi.org/10.1021/jacs.8b06789
State	Published - Sep 12 2018

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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Zhang, Y., Zhang, X., Lyu, J., Otake, K. I., Wang, X., Redfern, L. R., Malliakas, C. D., Li, Z., Islamoglu, T., Wang, B., & Farha, O. K. (2018). A Flexible Metal-Organic Framework with 4-Connected Zr ₆ Nodes Journal of the American Chemical Society, 140(36), 11179-11183. https://doi.org/10.1021/jacs.8b06789

Zhang, Yuanyuan ; Zhang, Xuan ; Lyu, Jiafei ; Otake, Ken Ichi ; Wang, Xingjie ; Redfern, Louis R. ; Malliakas, Christos D. ; Li, Zhanyong ; Islamoglu, Timur ; Wang, Bo ; Farha, Omar K. / A Flexible Metal-Organic Framework with 4-Connected Zr ₆ Nodes In: Journal of the American Chemical Society. 2018 ; Vol. 140, No. 36. pp. 11179-11183.

@article{9649102f235147208b3f2426eefab402,

title = " A Flexible Metal-Organic Framework with 4-Connected Zr 6 Nodes ",

abstract = " Zr-based metal-organic frameworks (MOFs) have been known for their excellent stability; however, due to the high connectivity of the Zr 6 nodes, it is challenging to introduce flexibility into Zr-MOFs. Here we present a flexible Zr-MOF named NU-1400 comprising 4-connected Zr 6 nodes and tetratopic linkers. It exhibits guest-dependent structural flexibility with up to 48% contraction in the unit cell volume as evidenced by single-crystal X-ray diffraction studies. The expanded or contracted conformations of NU-1400 showed drastically different reactivity toward the hydrolysis of a nerve agent simulant owing to the size-selective effect toward the reactant. ",

author = "Yuanyuan Zhang and Xuan Zhang and Jiafei Lyu and Otake, {Ken Ichi} and Xingjie Wang and Redfern, {Louis R.} and Malliakas, {Christos D.} and Zhanyong Li and Timur Islamoglu and Bo Wang and Farha, {Omar K.}",

year = "2018",

month = sep,

day = "12",

doi = "10.1021/jacs.8b06789",

language = "English (US)",

volume = "140",

pages = "11179--11183",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "36",

}

Zhang, Y, Zhang, X, Lyu, J, Otake, KI, Wang, X, Redfern, LR, Malliakas, CD, Li, Z, Islamoglu, T, Wang, B & Farha, OK 2018, ' A Flexible Metal-Organic Framework with 4-Connected Zr ₆ Nodes ', Journal of the American Chemical Society, vol. 140, no. 36, pp. 11179-11183. https://doi.org/10.1021/jacs.8b06789

A Flexible Metal-Organic Framework with 4-Connected Zr ₆ Nodes . / Zhang, Yuanyuan; Zhang, Xuan; Lyu, Jiafei; Otake, Ken Ichi; Wang, Xingjie; Redfern, Louis R.; Malliakas, Christos D.; Li, Zhanyong; Islamoglu, Timur; Wang, Bo; Farha, Omar K.

In: Journal of the American Chemical Society, Vol. 140, No. 36, 12.09.2018, p. 11179-11183.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - A Flexible Metal-Organic Framework with 4-Connected Zr 6 Nodes

AU - Zhang, Yuanyuan

AU - Zhang, Xuan

AU - Lyu, Jiafei

AU - Otake, Ken Ichi

AU - Wang, Xingjie

AU - Redfern, Louis R.

AU - Malliakas, Christos D.

AU - Li, Zhanyong

AU - Islamoglu, Timur

AU - Wang, Bo

AU - Farha, Omar K.

PY - 2018/9/12

Y1 - 2018/9/12

N2 - Zr-based metal-organic frameworks (MOFs) have been known for their excellent stability; however, due to the high connectivity of the Zr 6 nodes, it is challenging to introduce flexibility into Zr-MOFs. Here we present a flexible Zr-MOF named NU-1400 comprising 4-connected Zr 6 nodes and tetratopic linkers. It exhibits guest-dependent structural flexibility with up to 48% contraction in the unit cell volume as evidenced by single-crystal X-ray diffraction studies. The expanded or contracted conformations of NU-1400 showed drastically different reactivity toward the hydrolysis of a nerve agent simulant owing to the size-selective effect toward the reactant.

AB - Zr-based metal-organic frameworks (MOFs) have been known for their excellent stability; however, due to the high connectivity of the Zr 6 nodes, it is challenging to introduce flexibility into Zr-MOFs. Here we present a flexible Zr-MOF named NU-1400 comprising 4-connected Zr 6 nodes and tetratopic linkers. It exhibits guest-dependent structural flexibility with up to 48% contraction in the unit cell volume as evidenced by single-crystal X-ray diffraction studies. The expanded or contracted conformations of NU-1400 showed drastically different reactivity toward the hydrolysis of a nerve agent simulant owing to the size-selective effect toward the reactant.

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

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A Flexible Metal-Organic Framework with 4-Connected Zr 6 Nodes

Abstract

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A Flexible Metal-Organic Framework with 4-Connected Zr ₆ Nodes