A Flexible Metal-Organic Framework with 4-Connected Zr6 Nodes

Yuanyuan Zhang; Xuan Zhang; Jiafei Lyu; Ken Ichi Otake; Xingjie Wang; Louis R. Redfern; Christos D. Malliakas; Zhanyong Li; Timur Islamoglu; Bo Wang; Omar K. Farha

doi:10.1021/jacs.8b06789

A Flexible Metal-Organic Framework with 4-Connected Zr₆ Nodes

Yuanyuan Zhang, Xuan Zhang, Jiafei Lyu, Ken Ichi Otake, Xingjie Wang, Louis R. Redfern, Christos D. Malliakas, Zhanyong Li, Timur Islamoglu, Bo Wang, Omar K. Farha^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

173 Scopus citations

Abstract

Zr-based metal-organic frameworks (MOFs) have been known for their excellent stability; however, due to the high connectivity of the Zr₆ nodes, it is challenging to introduce flexibility into Zr-MOFs. Here we present a flexible Zr-MOF named NU-1400 comprising 4-connected Zr₆ nodes and tetratopic linkers. It exhibits guest-dependent structural flexibility with up to 48% contraction in the unit cell volume as evidenced by single-crystal X-ray diffraction studies. The expanded or contracted conformations of NU-1400 showed drastically different reactivity toward the hydrolysis of a nerve agent simulant owing to the size-selective effect toward the reactant.

Original language	English (US)
Pages (from-to)	11179-11183
Number of pages	5
Journal	Journal of the American Chemical Society
Volume	140
Issue number	36
DOIs	https://doi.org/10.1021/jacs.8b06789
State	Published - Sep 12 2018

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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10.1021/jacs.8b06789

Cite this

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title = "A Flexible Metal-Organic Framework with 4-Connected Zr6 Nodes",

abstract = "Zr-based metal-organic frameworks (MOFs) have been known for their excellent stability; however, due to the high connectivity of the Zr6 nodes, it is challenging to introduce flexibility into Zr-MOFs. Here we present a flexible Zr-MOF named NU-1400 comprising 4-connected Zr6 nodes and tetratopic linkers. It exhibits guest-dependent structural flexibility with up to 48% contraction in the unit cell volume as evidenced by single-crystal X-ray diffraction studies. The expanded or contracted conformations of NU-1400 showed drastically different reactivity toward the hydrolysis of a nerve agent simulant owing to the size-selective effect toward the reactant.",

author = "Yuanyuan Zhang and Xuan Zhang and Jiafei Lyu and Otake, {Ken Ichi} and Xingjie Wang and Redfern, {Louis R.} and Malliakas, {Christos D.} and Zhanyong Li and Timur Islamoglu and Bo Wang and Farha, {Omar K.}",

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AU - Zhang, Yuanyuan

AU - Zhang, Xuan

AU - Lyu, Jiafei

AU - Otake, Ken Ichi

AU - Wang, Xingjie

AU - Redfern, Louis R.

AU - Malliakas, Christos D.

AU - Li, Zhanyong

AU - Islamoglu, Timur

AU - Wang, Bo

AU - Farha, Omar K.

PY - 2018/9/12

Y1 - 2018/9/12

N2 - Zr-based metal-organic frameworks (MOFs) have been known for their excellent stability; however, due to the high connectivity of the Zr6 nodes, it is challenging to introduce flexibility into Zr-MOFs. Here we present a flexible Zr-MOF named NU-1400 comprising 4-connected Zr6 nodes and tetratopic linkers. It exhibits guest-dependent structural flexibility with up to 48% contraction in the unit cell volume as evidenced by single-crystal X-ray diffraction studies. The expanded or contracted conformations of NU-1400 showed drastically different reactivity toward the hydrolysis of a nerve agent simulant owing to the size-selective effect toward the reactant.

AB - Zr-based metal-organic frameworks (MOFs) have been known for their excellent stability; however, due to the high connectivity of the Zr6 nodes, it is challenging to introduce flexibility into Zr-MOFs. Here we present a flexible Zr-MOF named NU-1400 comprising 4-connected Zr6 nodes and tetratopic linkers. It exhibits guest-dependent structural flexibility with up to 48% contraction in the unit cell volume as evidenced by single-crystal X-ray diffraction studies. The expanded or contracted conformations of NU-1400 showed drastically different reactivity toward the hydrolysis of a nerve agent simulant owing to the size-selective effect toward the reactant.

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A Flexible Metal-Organic Framework with 4-Connected Zr₆ Nodes

Abstract

ASJC Scopus subject areas

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CCDC 1850690: Experimental Crystal Structure Determination

CCDC 1850691: Experimental Crystal Structure Determination

CCDC 1850693: Experimental Crystal Structure Determination

Cite this

A Flexible Metal-Organic Framework with 4-Connected Zr6 Nodes

Abstract

ASJC Scopus subject areas

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Datasets

CCDC 1850690: Experimental Crystal Structure Determination

CCDC 1850691: Experimental Crystal Structure Determination

CCDC 1850693: Experimental Crystal Structure Determination

Cite this

A Flexible Metal-Organic Framework with 4-Connected Zr₆ Nodes