A four-shell, 136-metal 3d-4f heterometallic cluster approximating a rectangular parallelepiped

Xiang Jian Kong; La Sheng Long; Rong Bin Huang; Lan Sun Zheng; T. David Harris; Zhiping Zheng

doi:10.1039/b822609a

A four-shell, 136-metal 3d-4f heterometallic cluster approximating a rectangular parallelepiped

Xiang Jian Kong, La Sheng Long^*, Rong Bin Huang, Lan Sun Zheng, T. David Harris, Zhiping Zheng

^*Corresponding author for this work

Chemistry

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92 Scopus citations

Abstract

A nanosized heterometallic cluster containing 60 La(iii) and 76 Ni(ii) ions, which are arranged into a four-shell, nest-like framework structure, was obtained by the hydrolytic reaction of the mixed La(NO₃) ₃-Ni(NO₃)₂ system using iminodiacetate as an ancillary ligand to control the hydrolysis.

Original language	English (US)
Pages (from-to)	4354-4356
Number of pages	3
Journal	Chemical Communications
Issue number	29
DOIs	https://doi.org/10.1039/b822609a
State	Published - Sep 18 2009

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/b822609a

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abstract = "A nanosized heterometallic cluster containing 60 La(iii) and 76 Ni(ii) ions, which are arranged into a four-shell, nest-like framework structure, was obtained by the hydrolytic reaction of the mixed La(NO3) 3-Ni(NO3)2 system using iminodiacetate as an ancillary ligand to control the hydrolysis.",

author = "Kong, {Xiang Jian} and Long, {La Sheng} and Huang, {Rong Bin} and Zheng, {Lan Sun} and Harris, {T. David} and Zhiping Zheng",

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AU - Kong, Xiang Jian

AU - Long, La Sheng

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AU - Zheng, Lan Sun

AU - Harris, T. David

AU - Zheng, Zhiping

PY - 2009/9/18

Y1 - 2009/9/18

N2 - A nanosized heterometallic cluster containing 60 La(iii) and 76 Ni(ii) ions, which are arranged into a four-shell, nest-like framework structure, was obtained by the hydrolytic reaction of the mixed La(NO3) 3-Ni(NO3)2 system using iminodiacetate as an ancillary ligand to control the hydrolysis.

AB - A nanosized heterometallic cluster containing 60 La(iii) and 76 Ni(ii) ions, which are arranged into a four-shell, nest-like framework structure, was obtained by the hydrolytic reaction of the mixed La(NO3) 3-Ni(NO3)2 system using iminodiacetate as an ancillary ligand to control the hydrolysis.

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A four-shell, 136-metal 3d-4f heterometallic cluster approximating a rectangular parallelepiped

Abstract

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