A heterogeneous, selective oxidation catalyst based on Mn triazacyclononane grafted under reaction conditions

Nicholas J. Schoenfeldt; Andrew W. Korinda; Justin M. Notestein

doi:10.1039/b920391e

A heterogeneous, selective oxidation catalyst based on Mn triazacyclononane grafted under reaction conditions

Nicholas J. Schoenfeldt, Andrew W. Korinda, Justin M. Notestein

Chemical and Biological Engineering

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

A unique method has been developed to synthesize an active heterogeneous oxidation catalyst by the in situ grafting of a 1,4,7-trimethyl-1,4,7- triazacyclononane manganese complex on carboxylic acid-functionalized supports serving dual roles as surface tether and necessary co-catalyst, massively increasing total turnovers as compared to the homogeneous analog.

Original language	English (US)
Pages (from-to)	1640-1642
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	10
DOIs	https://doi.org/10.1039/b920391e
State	Published - 2010

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Metals and Alloys
Materials Chemistry
Surfaces, Coatings and Films
General Chemistry
Catalysis

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10.1039/b920391e

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abstract = "A unique method has been developed to synthesize an active heterogeneous oxidation catalyst by the in situ grafting of a 1,4,7-trimethyl-1,4,7- triazacyclononane manganese complex on carboxylic acid-functionalized supports serving dual roles as surface tether and necessary co-catalyst, massively increasing total turnovers as compared to the homogeneous analog.",

author = "Schoenfeldt, {Nicholas J.} and Korinda, {Andrew W.} and Notestein, {Justin M.}",

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AU - Schoenfeldt, Nicholas J.

AU - Korinda, Andrew W.

AU - Notestein, Justin M.

PY - 2010

Y1 - 2010

N2 - A unique method has been developed to synthesize an active heterogeneous oxidation catalyst by the in situ grafting of a 1,4,7-trimethyl-1,4,7- triazacyclononane manganese complex on carboxylic acid-functionalized supports serving dual roles as surface tether and necessary co-catalyst, massively increasing total turnovers as compared to the homogeneous analog.

AB - A unique method has been developed to synthesize an active heterogeneous oxidation catalyst by the in situ grafting of a 1,4,7-trimethyl-1,4,7- triazacyclononane manganese complex on carboxylic acid-functionalized supports serving dual roles as surface tether and necessary co-catalyst, massively increasing total turnovers as compared to the homogeneous analog.

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A heterogeneous, selective oxidation catalyst based on Mn triazacyclononane grafted under reaction conditions

Abstract

ASJC Scopus subject areas

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