A highly modular and convergent approach for the synthesis of stimulant-responsive heteroligated cofacial porphyrin tweezer complexes

Christopher G. Oliveri; Son Binh T. Nguyen; Chad A. Mirkin

doi:10.1021/ic702150y

A highly modular and convergent approach for the synthesis of stimulant-responsive heteroligated cofacial porphyrin tweezer complexes

Christopher G. Oliveri, Son Binh T. Nguyen, Chad A. Mirkin

Chemistry

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

The synthesis of new hemilabile phosphine ligands and their reaction with [Rh(COE)₂Cl]₂ to form dissymmetric heteroligated tweezer complexes using a halide-induced ligand rearrangement reaction are reported. These complexes can undergo reactions with small-molecule ligands and elemental anions quantitatively in situ, which serve to regulate the porphyrin-porphyrin distances and interactions within the assembly.

Original language	English (US)
Pages (from-to)	2755-2763
Number of pages	9
Journal	Inorganic chemistry
Volume	47
Issue number	7
DOIs	https://doi.org/10.1021/ic702150y
State	Published - Apr 7 2008

ASJC Scopus subject areas

Inorganic Chemistry
Physical and Theoretical Chemistry

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10.1021/ic702150y

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abstract = "The synthesis of new hemilabile phosphine ligands and their reaction with [Rh(COE)2Cl]2 to form dissymmetric heteroligated tweezer complexes using a halide-induced ligand rearrangement reaction are reported. These complexes can undergo reactions with small-molecule ligands and elemental anions quantitatively in situ, which serve to regulate the porphyrin-porphyrin distances and interactions within the assembly.",

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AU - Oliveri, Christopher G.

AU - Nguyen, Son Binh T.

AU - Mirkin, Chad A.

PY - 2008/4/7

Y1 - 2008/4/7

N2 - The synthesis of new hemilabile phosphine ligands and their reaction with [Rh(COE)2Cl]2 to form dissymmetric heteroligated tweezer complexes using a halide-induced ligand rearrangement reaction are reported. These complexes can undergo reactions with small-molecule ligands and elemental anions quantitatively in situ, which serve to regulate the porphyrin-porphyrin distances and interactions within the assembly.

AB - The synthesis of new hemilabile phosphine ligands and their reaction with [Rh(COE)2Cl]2 to form dissymmetric heteroligated tweezer complexes using a halide-induced ligand rearrangement reaction are reported. These complexes can undergo reactions with small-molecule ligands and elemental anions quantitatively in situ, which serve to regulate the porphyrin-porphyrin distances and interactions within the assembly.

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A highly modular and convergent approach for the synthesis of stimulant-responsive heteroligated cofacial porphyrin tweezer complexes

Abstract

ASJC Scopus subject areas

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