@article{3659c5f884ed467596364bbb9cd362ee,
title = "A historical perspective on porphyrin-based metal–organic frameworks and their applications",
abstract = "Porphyrins are important molecules widely found in nature in the form of enzyme active sites and visible light absorption units. Recent interest in using these functional molecules as building blocks for the construction of metal–organic frameworks (MOFs) have rapidly increased due to the ease in which the locations of, and the distances between, the porphyrin units can be controlled in these porous crystalline materials. Porphyrin-based MOFs with atomically precise structures provide an ideal platform for the investigation of their structure–function relationships in the solid state without compromising accessibility to the inherent properties of the porphyrin building blocks. This review will provide a historical overview of the development and applications of porphyrin-based MOFs from early studies focused on design and structures, to recent efforts on their utilization in biomimetic catalysis, photocatalysis, electrocatalysis, sensing, and biomedical applications.",
keywords = "Biomedical applications, Catalysis, Metal–organic frameworks, Porphyrin, Sensing",
author = "Xuan Zhang and Wasson, {Megan C.} and Mohsen Shayan and Berdichevsky, {Ellan K.} and Joseph Ricardo-Noordberg and Zujhar Singh and Papazyan, {Edgar K.} and Castro, {Anthony J.} and Paola Marino and Zvart Ajoyan and Zhijie Chen and Timur Islamoglu and Howarth, {Ashlee J.} and Yangyang Liu and Majewski, {Marek B.} and Katz, {Michael J.} and Mondloch, {Joseph E.} and Farha, {Omar K.}",
note = "Funding Information: O.K.F. acknowledges support from Defense Threat Reduction Agency (HDTRA1-18-1-0003, HDTRA1-19-1-0007, HDTRA1-19-1-0010); Army Research Office (W911NF1910340); the Inorganometallic Catalyst Design Center, an EFRC funded by the DOE, Office of Science, Basic Energy Sciences (DE-SC0012702); the U.S. Department of Energy, National Nuclear Security Administration, under Award Number DE-NA0003763; the Northwestern University Institute for Catalysis in Energy Processes (ICEP), funded by the DOE, Office of Basic Energy Sciences (Award Number DE-FG02-03ER15457); the Air Force Research Laboratory (FA8650-15-2-5518); the U. S. Department of Energy (DOE) Office of Science, Basic Energy Sciences Program for Separation (DE-FG02-08ER15967), and Northwestern University. M.J.K. would like to acknowledge the Natural Sciences and Engineering Research Council (NSERC) of Canada for a Discovery Grant. J.R.N. Z.S. M.B.M. thank the Natural Sciences and Engineering Research Council of Canada (NSERC) and the Fonds de Recherche du Qu{\'e}bec – Nature et technologies (FRQNT). AJH acknowledges the support of the Natural Sciences and Engineering Research Council of Canada (NSERC), [funding reference number: DGECR‐2018 00344]. Cette recherche a {\'e}t{\'e} financ{\'e}e par le Conseil de recherches en sciences naturelles et en g{\'e}nie du Canada (CRSNG), [num{\'e}ro de reference: DGECR‐2018‐00344]. Y.L. gratefully acknowledges the financial support from Army Research Office (W911NF-19-1-0001). A.J.C. is supported by the National Institute of General Medical Sciences of the National Institute of Health (R25GM061331). E.K.P. is supported by American Chemical Society Petroleum Research Fund (57951-UNI10). M.C.W. is supported by the NSF Graduate Research Fellowship under grant DGE-1842165. Funding Information: O.K.F. acknowledges support from Defense Threat Reduction Agency ( HDTRA1-18-1-0003 , HDTRA1-19-1-0007 , HDTRA1-19-1-0010 ); Army Research Office ( W911NF1910340 ); the Inorganometallic Catalyst Design Center, an EFRC funded by the DOE , Office of Science , Basic Energy Sciences ( DE-SC0012702 ); the U.S. Department of Energy , National Nuclear Security Administration , under Award Number DE-NA0003763 ; the Northwestern University Institute for Catalysis in Energy Processes (ICEP), funded by the DOE , Office of Basic Energy Sciences (Award Number DE-FG02-03ER15457 ); the Air Force Research Laboratory ( FA8650-15-2-5518 ); the U. S. Department of Energy (DOE) Office of Science , Basic Energy Sciences Program for Separation ( DE-FG02-08ER15967 ), and Northwestern University . M.J.K. would like to acknowledge the Natural Sciences and Engineering Research Council ( NSERC ) of Canada for a Discovery Grant. J.R.N., Z.S., M.B.M. thank the Natural Sciences and Engineering Research Council of Canada (NSERC) and the Fonds de Recherche du Qu{\'e}bec – Nature et technologies ( FRQNT ). AJH acknowledges the support of the Natural Sciences and Engineering Research Council of Canada (NSERC), [funding reference number: DGECR‐ 2018 00344 ]. Cette recherche a {\'e}t{\'e} financ{\'e}e par le Conseil de recherches en sciences naturelles et en g{\'e}nie du Canada (CRSNG), [num{\'e}ro de reference: DGECR‐ 2018‐00344]. Y.L. gratefully acknowledges the financial support from Army Research Office ( W911NF-19-1-0001 ). A.J.C. is supported by the National Institute of General Medical Sciences of the National Institute of Health ( R25GM061331 ). E.K.P. is supported by American Chemical Society Petroleum Research Fund ( 57951-UNI10 ). M.C.W. is supported by the NSF Graduate Research Fellowship under grant DGE - 1842165 . Publisher Copyright: {\textcopyright} 2020 Elsevier B.V.",
year = "2021",
month = feb,
day = "15",
doi = "10.1016/j.ccr.2020.213615",
language = "English (US)",
volume = "429",
journal = "Coordination Chemistry Reviews",
issn = "0010-8545",
publisher = "Elsevier",
}