A Macrobicyclic Receptor Molecule for the Diquat Dication

Billy L. Allwood; Franz H. Kohnke; J. Fraser Stoddart; David J. Williams

doi:10.1002/anie.198505811

A Macrobicyclic Receptor Molecule for the Diquat Dication

Billy L. Allwood, Franz H. Kohnke, J. Fraser Stoddart^*, David J. Williams

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

A 1:1 complex of [diquat]²⁺ and a tailor‐made derivative of dibenzo[30]crown‐10 has been investigated in solution as well as in the solid phase. The crown ether is rigidified by an o‐(CH₂O)₂C₆H₄ bridge joining the two annelated benzene rings. Complicated exchange reactions in solution were studied NMR spectroscopically. X‐ray structure analyses have been carried out on the host molecule and the complex.

Original language	English (US)
Pages (from-to)	581-584
Number of pages	4
Journal	Angewandte Chemie International Edition in English
Volume	24
Issue number	7
DOIs	https://doi.org/10.1002/anie.198505811
State	Published - Jan 1 1985

ASJC Scopus subject areas

Catalysis
Chemistry(all)

Access to Document

10.1002/anie.198505811

Cite this

@article{f2c97000d8a243a3b92574dafe6acd6c,

title = "A Macrobicyclic Receptor Molecule for the Diquat Dication",

abstract = "A 1:1 complex of [diquat]2+ and a tailor‐made derivative of dibenzo[30]crown‐10 has been investigated in solution as well as in the solid phase. The crown ether is rigidified by an o‐(CH2O)2C6H4 bridge joining the two annelated benzene rings. Complicated exchange reactions in solution were studied NMR spectroscopically. X‐ray structure analyses have been carried out on the host molecule and the complex.",

author = "Allwood, {Billy L.} and Kohnke, {Franz H.} and Stoddart, {J. Fraser} and Williams, {David J.}",

year = "1985",

month = jan,

day = "1",

doi = "10.1002/anie.198505811",

language = "English (US)",

volume = "24",

pages = "581--584",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "7",

}

TY - JOUR

T1 - A Macrobicyclic Receptor Molecule for the Diquat Dication

AU - Allwood, Billy L.

AU - Kohnke, Franz H.

AU - Stoddart, J. Fraser

AU - Williams, David J.

PY - 1985/1/1

Y1 - 1985/1/1

N2 - A 1:1 complex of [diquat]2+ and a tailor‐made derivative of dibenzo[30]crown‐10 has been investigated in solution as well as in the solid phase. The crown ether is rigidified by an o‐(CH2O)2C6H4 bridge joining the two annelated benzene rings. Complicated exchange reactions in solution were studied NMR spectroscopically. X‐ray structure analyses have been carried out on the host molecule and the complex.

AB - A 1:1 complex of [diquat]2+ and a tailor‐made derivative of dibenzo[30]crown‐10 has been investigated in solution as well as in the solid phase. The crown ether is rigidified by an o‐(CH2O)2C6H4 bridge joining the two annelated benzene rings. Complicated exchange reactions in solution were studied NMR spectroscopically. X‐ray structure analyses have been carried out on the host molecule and the complex.

UR - http://www.scopus.com/inward/record.url?scp=84985594989&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84985594989&partnerID=8YFLogxK

U2 - 10.1002/anie.198505811

DO - 10.1002/anie.198505811

M3 - Article

AN - SCOPUS:84985594989

VL - 24

SP - 581

EP - 584

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 7

ER -

A Macrobicyclic Receptor Molecule for the Diquat Dication

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this