A neutral naphthalene diimide [2]rotaxane

Henri Pierre Jacquot De Rouville; Julien Iehl; Carson J. Bruns; Psaras L. McGrier; Marco Frasconi; Amy A. Sarjeant; J Fraser Stoddart

doi:10.1021/ol3022963

A neutral naphthalene diimide [2]rotaxane

Henri Pierre Jacquot De Rouville, Julien Iehl, Carson J. Bruns, Psaras L. McGrier, Marco Frasconi, Amy A. Sarjeant, J Fraser Stoddart^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

A neutral donor-acceptor [2]rotaxane, which has been synthesized using click chemistry, has had its solid-state structure and superstructure elucidated by X-ray crystallography. Both dynamic ¹H NMR spectroscopy and electrochemical investigations have been employed in an attempt to shed light on both geometrical reorganization and redox-switching processes that are occurring or can be induced within the [2]rotaxane.

Original language	English (US)
Pages (from-to)	5188-5191
Number of pages	4
Journal	Organic Letters
Volume	14
Issue number	20
DOIs	https://doi.org/10.1021/ol3022963
State	Published - Oct 19 2012

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol3022963

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abstract = "A neutral donor-acceptor [2]rotaxane, which has been synthesized using click chemistry, has had its solid-state structure and superstructure elucidated by X-ray crystallography. Both dynamic 1H NMR spectroscopy and electrochemical investigations have been employed in an attempt to shed light on both geometrical reorganization and redox-switching processes that are occurring or can be induced within the [2]rotaxane.",

author = "{Jacquot De Rouville}, {Henri Pierre} and Julien Iehl and Bruns, {Carson J.} and McGrier, {Psaras L.} and Marco Frasconi and Sarjeant, {Amy A.} and Stoddart, {J Fraser}",

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AU - Jacquot De Rouville, Henri Pierre

AU - Iehl, Julien

AU - Bruns, Carson J.

AU - McGrier, Psaras L.

AU - Frasconi, Marco

AU - Sarjeant, Amy A.

AU - Stoddart, J Fraser

PY - 2012/10/19

Y1 - 2012/10/19

N2 - A neutral donor-acceptor [2]rotaxane, which has been synthesized using click chemistry, has had its solid-state structure and superstructure elucidated by X-ray crystallography. Both dynamic 1H NMR spectroscopy and electrochemical investigations have been employed in an attempt to shed light on both geometrical reorganization and redox-switching processes that are occurring or can be induced within the [2]rotaxane.

AB - A neutral donor-acceptor [2]rotaxane, which has been synthesized using click chemistry, has had its solid-state structure and superstructure elucidated by X-ray crystallography. Both dynamic 1H NMR spectroscopy and electrochemical investigations have been employed in an attempt to shed light on both geometrical reorganization and redox-switching processes that are occurring or can be induced within the [2]rotaxane.

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A neutral naphthalene diimide [2]rotaxane

Abstract

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