A new crystal: Layer-structured rhombohedral In3Se4

Guang Han, Zhi Gang Chen, Chenghua Sun, Lei Yang, Lina Cheng, Zhifeng Li, Wei Lu, Zachary M. Gibbs, G. Jeffery Snyder, Kevin Jack, John Drennan, Jin Zou

Research output: Contribution to journalArticlepeer-review

23 Scopus citations

Abstract

A new layer-structured rhombohedral In3Se4 crystal was synthesized by a facile and mild solvothermal method. Detailed structural and chemical characterizations using transmission electron microscopy, coupled with synchrotron X-ray diffraction analysis and Rietveld refinement, indicate that In3Se4 crystallizes in a layered rhombohedral structure with lattice parameters of a = 3.964 ± 0.002 Å and c = 39.59 ± 0.02 Å, a space group of R3m, and with a layer composition of Se-In-Se-In-Se-In-Se. The theoretical modeling and experimental measurements indicate that the In3Se4 is a self-doped n-type semiconductor. This study not only enriches the understanding on crystallography of indium selenide crystals, but also paves a way in the search for new semiconducting compounds.

Original languageEnglish (US)
Pages (from-to)393-398
Number of pages6
JournalCrystEngComm
Volume16
Issue number3
DOIs
StatePublished - Jan 21 2014

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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