TY - JOUR
T1 - A new mononuclear thiolato nickel(II) square planar complex with an uncommon (S2NO) coordination
AU - Kanatzidis, Mercouri G.
N1 - Funding Information:
I thank Dr. Don Ward for assistance in the crystallographic data collection and structure solution. Support by the Biomedical Research Support Grant awarded by the Public Health Service, National Institutes of Health is gratefully acknowledged.
PY - 1990/2/1
Y1 - 1990/2/1
N2 - The synthesis, structure, spectra and properties of (Ph4P)[Ni(MSA)(SPh)] (tetraphenylphosphonium 2-(2-mercaptophenyl)salicyladiminato thiophenolato nickelate(II)) (I) are reported. The compound crystallizes as red needles in the monoclinic spaces group P21/c with cell dimensions a = 10.813(6), b = 17.061(6), c = 19.873(10) Å, β = 100.06(5)°, V = 3610(3) Å3, Z = 4. The structure was solved by conventional methods using 4919 reflections and refined to R = 5.7% and Rw = 6.6%. The complex features a square planar Ni2+ environment in which the metal center is bound to two sulfur, a nitrogen an an oxygen atom. The corresponding phenolato complex (Ph4P)[Ni(MSA)(OPh)] (II) is X-ray isomorphous to I. The electronic spectra and electrochemical properties of I and II are discussed.
AB - The synthesis, structure, spectra and properties of (Ph4P)[Ni(MSA)(SPh)] (tetraphenylphosphonium 2-(2-mercaptophenyl)salicyladiminato thiophenolato nickelate(II)) (I) are reported. The compound crystallizes as red needles in the monoclinic spaces group P21/c with cell dimensions a = 10.813(6), b = 17.061(6), c = 19.873(10) Å, β = 100.06(5)°, V = 3610(3) Å3, Z = 4. The structure was solved by conventional methods using 4919 reflections and refined to R = 5.7% and Rw = 6.6%. The complex features a square planar Ni2+ environment in which the metal center is bound to two sulfur, a nitrogen an an oxygen atom. The corresponding phenolato complex (Ph4P)[Ni(MSA)(OPh)] (II) is X-ray isomorphous to I. The electronic spectra and electrochemical properties of I and II are discussed.
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U2 - 10.1016/S0020-1693(00)88023-8
DO - 10.1016/S0020-1693(00)88023-8
M3 - Article
AN - SCOPUS:3242801674
SN - 0020-1693
VL - 168
SP - 101
EP - 103
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
IS - 1
ER -