TY - JOUR
T1 - A novel phase transition in conductive molecular crystals based on metal bis-diselenoalkene complexes
T2 - [TMTSF]2[M(Se2C2(CF3)2]; M = Ni, Pt; TMTSF = tetramethyltetraselenafulvalene
AU - Heuer, William B.
AU - Hoffman, Brian M.
PY - 1986
Y1 - 1986
N2 - Single crystals of [TMTSF]2[M(Se2C2(CF3)2)2](TMTSF = tetramethyltetraselenafulvalene; M = Ni, Pt) have room-temperature conductivities of 20–65 Ω;–1 cm–1 and upon cooling undergo an unprecedented phase transition in which the low temperature phase shows enhanced electrical conductivity: M = Ni, Tc=ca. 275 K; M = Pt, Tc=ca. 245 K.
AB - Single crystals of [TMTSF]2[M(Se2C2(CF3)2)2](TMTSF = tetramethyltetraselenafulvalene; M = Ni, Pt) have room-temperature conductivities of 20–65 Ω;–1 cm–1 and upon cooling undergo an unprecedented phase transition in which the low temperature phase shows enhanced electrical conductivity: M = Ni, Tc=ca. 275 K; M = Pt, Tc=ca. 245 K.
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U2 - 10.1039/C39860000174
DO - 10.1039/C39860000174
M3 - Article
AN - SCOPUS:37049075416
SN - 0022-4936
SP - 174
EP - 175
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
ER -