A rate constant expression was presented for charge transfer reactions mediated by flexible bridges. It was found that the leading term corresponds to the static limit which was obtained from the Condon approximation. The corrections due to finite time fluctuations were also evaluated.
|Original language||English (US)|
|Number of pages||7|
|Journal||Journal of Chemical Physics|
|State||Published - Sep 22 2003|
ASJC Scopus subject areas
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry