A rate constant expression for charge transfer through fluctuating bridges

Alessandro Troisi; Abraham Nitzan; Mark A. Ratner

doi:10.1063/1.1601600

A rate constant expression for charge transfer through fluctuating bridges

Alessandro Troisi^*, Abraham Nitzan, Mark A. Ratner

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

134 Scopus citations

Abstract

A rate constant expression was presented for charge transfer reactions mediated by flexible bridges. It was found that the leading term corresponds to the static limit which was obtained from the Condon approximation. The corrections due to finite time fluctuations were also evaluated.

Original language	English (US)
Pages (from-to)	5782-5788
Number of pages	7
Journal	Journal of Chemical Physics
Volume	119
Issue number	12
DOIs	https://doi.org/10.1063/1.1601600
State	Published - Sep 22 2003

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

Access to Document

10.1063/1.1601600

Cite this

@article{f7363520671948a09a7bf7882f1a7630,

title = "A rate constant expression for charge transfer through fluctuating bridges",

abstract = "A rate constant expression was presented for charge transfer reactions mediated by flexible bridges. It was found that the leading term corresponds to the static limit which was obtained from the Condon approximation. The corrections due to finite time fluctuations were also evaluated.",

author = "Alessandro Troisi and Abraham Nitzan and Ratner, {Mark A.}",

year = "2003",

month = sep,

day = "22",

doi = "10.1063/1.1601600",

language = "English (US)",

volume = "119",

pages = "5782--5788",

journal = "Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics",

number = "12",

}

TY - JOUR

T1 - A rate constant expression for charge transfer through fluctuating bridges

AU - Troisi, Alessandro

AU - Nitzan, Abraham

AU - Ratner, Mark A.

PY - 2003/9/22

Y1 - 2003/9/22

N2 - A rate constant expression was presented for charge transfer reactions mediated by flexible bridges. It was found that the leading term corresponds to the static limit which was obtained from the Condon approximation. The corrections due to finite time fluctuations were also evaluated.

AB - A rate constant expression was presented for charge transfer reactions mediated by flexible bridges. It was found that the leading term corresponds to the static limit which was obtained from the Condon approximation. The corrections due to finite time fluctuations were also evaluated.

UR - http://www.scopus.com/inward/record.url?scp=0142059000&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0142059000&partnerID=8YFLogxK

U2 - 10.1063/1.1601600

DO - 10.1063/1.1601600

M3 - Article

AN - SCOPUS:0142059000

SN - 0021-9606

VL - 119

SP - 5782

EP - 5788

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 12

ER -

A rate constant expression for charge transfer through fluctuating bridges

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this