A review of the shear rheology of carbon black suspensions

Jeffrey J. Richards*, Paolo Z. Ramos, Qingsong Liu

*Corresponding author for this work

Research output: Contribution to journalReview articlepeer-review

Abstract

The microstructural link to the rheology of carbon black suspensions has recently become clear as a result of advances in computational and experimental methods. This understanding reveals the important role of the restructuring, build-up, and break-up of carbon black agglomerates in simple shear, rationalized by a dimensionless balance of the hydrodynamic forces acting to break the agglomerates apart against the cohesive forces holding them together (i.e., the Mason number). The Mason number not only can predict the origin of reversible thixotropy seen in carbon black suspensions observed at higher shear intensities, but can also be used to rationalize the evolution of microstructure at lower shear intensities. This review focuses on carbon black suspension behavior, but the insights derived from carbon black suspensions are broadly applicable to a diverse class of soft matter including colloidal gels relevant to a variety of applications.

Original languageEnglish (US)
Article number1245847
JournalFrontiers in Physics
Volume11
DOIs
StatePublished - 2023

Keywords

  • antithixotropy
  • carbon black
  • microstructure
  • rheology
  • rheopexy
  • suspension
  • thixotropy

ASJC Scopus subject areas

  • Biophysics
  • Materials Science (miscellaneous)
  • Mathematical Physics
  • General Physics and Astronomy
  • Physical and Theoretical Chemistry

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