A self-catalyzing hydrogen-storage material

Jun Yang; Andrea Sudik; Donald J. Siegel; Devin Halliday; Andrew Drews; Roscoe O. Carter; Christopher Wolverton; Gregory J. Lewis; J. W.Adriaan Sachtler; John J. Low; Syed A. Faheem; David A. Lesch; Vidvuds Ozolinš

doi:10.1002/anie.200703756

A self-catalyzing hydrogen-storage material

Jun Yang^*, Andrea Sudik, Donald J. Siegel, Devin Halliday, Andrew Drews, Roscoe O. Carter, Christopher Wolverton, Gregory J. Lewis, J. W.Adriaan Sachtler, John J. Low, Syed A. Faheem, David A. Lesch, Vidvuds Ozolinš

^*Corresponding author for this work

Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

132 Scopus citations

Abstract

(Graph Presented) Greater than the sum of its parts: Hydrogen storage in complex hydrides is accelerated by using the ternary composite 2 LiNH ₂/LiBH₄/MgH₂, which exhibits a "self-catalyzing" reaction pathway that results in faster H ₂ desorption, lower desorption temperatures, and suppression of NH₃ release in comparison to the constituent binary composites (see diagram). The enhanced properties arise from the incorporation of an ionic liquid phase (Li₄BH₃H₁₀) and from ancillary-reaction seeding of a reversible H₂ storage reaction.

Original language	English (US)
Pages (from-to)	882-887
Number of pages	6
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	5
DOIs	https://doi.org/10.1002/anie.200703756
State	Published - 2008

Keywords

Hydrides
Hydrogen storage
Kinetics
Materials science
Thermodynamics

ASJC Scopus subject areas

General Chemistry
Catalysis

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10.1002/anie.200703756

Cite this

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keywords = "Hydrides, Hydrogen storage, Kinetics, Materials science, Thermodynamics",

author = "Jun Yang and Andrea Sudik and Siegel, {Donald J.} and Devin Halliday and Andrew Drews and Carter, {Roscoe O.} and Christopher Wolverton and Lewis, {Gregory J.} and Sachtler, {J. W.Adriaan} and Low, {John J.} and Faheem, {Syed A.} and Lesch, {David A.} and Vidvuds Ozolin{\v s}",

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T1 - A self-catalyzing hydrogen-storage material

AU - Yang, Jun

AU - Sudik, Andrea

AU - Siegel, Donald J.

AU - Halliday, Devin

AU - Drews, Andrew

AU - Carter, Roscoe O.

AU - Wolverton, Christopher

AU - Lewis, Gregory J.

AU - Sachtler, J. W.Adriaan

AU - Low, John J.

AU - Faheem, Syed A.

AU - Lesch, David A.

AU - Ozolinš, Vidvuds

PY - 2008

Y1 - 2008

N2 - (Graph Presented) Greater than the sum of its parts: Hydrogen storage in complex hydrides is accelerated by using the ternary composite 2 LiNH 2/LiBH4/MgH2, which exhibits a "self-catalyzing" reaction pathway that results in faster H 2 desorption, lower desorption temperatures, and suppression of NH3 release in comparison to the constituent binary composites (see diagram). The enhanced properties arise from the incorporation of an ionic liquid phase (Li4BH3H10) and from ancillary-reaction seeding of a reversible H2 storage reaction.

AB - (Graph Presented) Greater than the sum of its parts: Hydrogen storage in complex hydrides is accelerated by using the ternary composite 2 LiNH 2/LiBH4/MgH2, which exhibits a "self-catalyzing" reaction pathway that results in faster H 2 desorption, lower desorption temperatures, and suppression of NH3 release in comparison to the constituent binary composites (see diagram). The enhanced properties arise from the incorporation of an ionic liquid phase (Li4BH3H10) and from ancillary-reaction seeding of a reversible H2 storage reaction.

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KW - Hydrogen storage

KW - Kinetics

KW - Materials science

KW - Thermodynamics

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A self-catalyzing hydrogen-storage material

Abstract

Keywords

ASJC Scopus subject areas

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