A self-complexing [2]catenane

Beatriz Cabezon; Jianguo Cao; Françisco M. Raymo; J. Fraser Stoddart; Andrew J P White; David J. Williams

doi:10.1002/(SICI)1521-3773(20000103)39:1<148::AID-ANIE148>3.0.CO;2-7

A self-complexing [2]catenane

Beatriz Cabezon, Jianguo Cao, Françisco M. Raymo, J. Fraser Stoddart^*, Andrew J P White, David J. Williams

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

A supramolecular homodimer is formed in solution and in the solid state by a self-complementary [2]catenane incorporating a 1,5-dioxynaphthalene- based macrocyclic polyether interlocked with a bipyridinium-based tetracationic cyclophane (shown schematically). This unique example of self- recognition is the result of a combination of cooperative π···π and C- H···π interactions.

Original language	English (US)
Pages (from-to)	148-151
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	39
Issue number	1
DOIs	https://doi.org/10.1002/(SICI)1521-3773(20000103)39:1<148::AID-ANIE148>3.0.CO;2-7
State	Published - Jan 3 2000

Keywords

Catenanes
Homodimeric complexes
Molecular recognition
Supramolecular chemistry

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/(SICI)1521-3773(20000103)39:1<148::AID-ANIE148>3.0.CO;2-7

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title = "A self-complexing [2]catenane",

abstract = "A supramolecular homodimer is formed in solution and in the solid state by a self-complementary [2]catenane incorporating a 1,5-dioxynaphthalene- based macrocyclic polyether interlocked with a bipyridinium-based tetracationic cyclophane (shown schematically). This unique example of self- recognition is the result of a combination of cooperative π···π and C- H···π interactions.",

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T1 - A self-complexing [2]catenane

AU - Cabezon, Beatriz

AU - Cao, Jianguo

AU - Raymo, Françisco M.

AU - Stoddart, J. Fraser

AU - White, Andrew J P

AU - Williams, David J.

PY - 2000/1/3

Y1 - 2000/1/3

N2 - A supramolecular homodimer is formed in solution and in the solid state by a self-complementary [2]catenane incorporating a 1,5-dioxynaphthalene- based macrocyclic polyether interlocked with a bipyridinium-based tetracationic cyclophane (shown schematically). This unique example of self- recognition is the result of a combination of cooperative π···π and C- H···π interactions.

AB - A supramolecular homodimer is formed in solution and in the solid state by a self-complementary [2]catenane incorporating a 1,5-dioxynaphthalene- based macrocyclic polyether interlocked with a bipyridinium-based tetracationic cyclophane (shown schematically). This unique example of self- recognition is the result of a combination of cooperative π···π and C- H···π interactions.

KW - Catenanes

KW - Homodimeric complexes

KW - Molecular recognition

KW - Supramolecular chemistry

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DO - 10.1002/(SICI)1521-3773(20000103)39:1<148::AID-ANIE148>3.0.CO;2-7

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A self-complexing [2]catenane

Abstract

Keywords

ASJC Scopus subject areas

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