A soliton phenomenon in langmuir monolayers of amphiphilic bistable rotaxanes

Paula M. Mendes, Weixing Lu, Hsian Rong Tseng, Sam Shinder, Takahiro Iijima, Masaaki Miyaji, Charles M. Knobler*, J. Fraser Stoddart

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

14 Scopus citations

Abstract

Surface pressure - area isotherms, light scattering microscopy, and atomic force microscopy have all been used to provide information about the stabilities and dynamics of Langmuir monolayers composed of amphiphilic bistable [2]rotaxane molecules. Superstructures that have the appearance of localized mobile solitons are formed during the compression of monolayers of the [2]rotaxanes below their collapse pressures. Solitons move solely in a linear trajectory in both directions across the film, perpendicular to the compression direction, without any apparent broadening or change in their shape.

Original languageEnglish (US)
Pages (from-to)3845-3848
Number of pages4
JournalJournal of Physical Chemistry B
Volume110
Issue number9
DOIs
StatePublished - Mar 9 2006

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films
  • Materials Chemistry

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