A straight forward route for the development of metal-organic frameworks functionalized with aromatic-OH groups: Synthesis, characterization, and gas (N2, Ar, H2, CO2, CH4, NH 3) sorption properties

Ioannis Spanopoulos; Pantelis Xydias; Christos D. Malliakas; Pantelis N. Trikalitis

doi:10.1021/ic302010e

A straight forward route for the development of metal-organic frameworks functionalized with aromatic-OH groups: Synthesis, characterization, and gas (N₂, Ar, H₂, CO₂, CH₄, NH ₃) sorption properties

Ioannis Spanopoulos, Pantelis Xydias, Christos D. Malliakas, Pantelis N. Trikalitis^*

^*Corresponding author for this work

Chemistry

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114 Scopus citations

Abstract

A facile and general methodology for the development of metal-organic frameworks (MOFs) functionalized with pendant, aromatic hydroxyl (-OH) groups is presented. Extensive gas-sorption studies in representative and important MOFs functionalized with free aromatic-OH groups such as the IRMOF-8 and DUT-6 (or MOF-205), denoted here as 1 and 2, revealed a high CO₂/CH₄ selectivity for 1 (13.6 at 273 K and 1 bar) and a high NH₃ uptake of 16.4 mol kg^-1 at 298 K and 1 bar for 2.

Original language	English (US)
Pages (from-to)	855-862
Number of pages	8
Journal	Inorganic chemistry
Volume	52
Issue number	2
DOIs	https://doi.org/10.1021/ic302010e
State	Published - Jan 18 2013

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic302010e

Cite this

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title = "A straight forward route for the development of metal-organic frameworks functionalized with aromatic-OH groups: Synthesis, characterization, and gas (N2, Ar, H2, CO2, CH4, NH 3) sorption properties",

abstract = "A facile and general methodology for the development of metal-organic frameworks (MOFs) functionalized with pendant, aromatic hydroxyl (-OH) groups is presented. Extensive gas-sorption studies in representative and important MOFs functionalized with free aromatic-OH groups such as the IRMOF-8 and DUT-6 (or MOF-205), denoted here as 1 and 2, revealed a high CO2/CH4 selectivity for 1 (13.6 at 273 K and 1 bar) and a high NH3 uptake of 16.4 mol kg-1 at 298 K and 1 bar for 2.",

author = "Ioannis Spanopoulos and Pantelis Xydias and Malliakas, {Christos D.} and Trikalitis, {Pantelis N.}",

year = "2013",

month = jan,

day = "18",

doi = "10.1021/ic302010e",

language = "English (US)",

volume = "52",

pages = "855--862",

journal = "Inorganic chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "2",

}

A straight forward route for the development of metal-organic frameworks functionalized with aromatic-OH groups: Synthesis, characterization, and gas (N₂, Ar, H₂, CO₂, CH₄, NH ₃) sorption properties. / Spanopoulos, Ioannis; Xydias, Pantelis; Malliakas, Christos D. et al.
In: Inorganic chemistry, Vol. 52, No. 2, 18.01.2013, p. 855-862.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - A straight forward route for the development of metal-organic frameworks functionalized with aromatic-OH groups

T2 - Synthesis, characterization, and gas (N2, Ar, H2, CO2, CH4, NH 3) sorption properties

AU - Spanopoulos, Ioannis

AU - Xydias, Pantelis

AU - Malliakas, Christos D.

AU - Trikalitis, Pantelis N.

PY - 2013/1/18

Y1 - 2013/1/18

N2 - A facile and general methodology for the development of metal-organic frameworks (MOFs) functionalized with pendant, aromatic hydroxyl (-OH) groups is presented. Extensive gas-sorption studies in representative and important MOFs functionalized with free aromatic-OH groups such as the IRMOF-8 and DUT-6 (or MOF-205), denoted here as 1 and 2, revealed a high CO2/CH4 selectivity for 1 (13.6 at 273 K and 1 bar) and a high NH3 uptake of 16.4 mol kg-1 at 298 K and 1 bar for 2.

AB - A facile and general methodology for the development of metal-organic frameworks (MOFs) functionalized with pendant, aromatic hydroxyl (-OH) groups is presented. Extensive gas-sorption studies in representative and important MOFs functionalized with free aromatic-OH groups such as the IRMOF-8 and DUT-6 (or MOF-205), denoted here as 1 and 2, revealed a high CO2/CH4 selectivity for 1 (13.6 at 273 K and 1 bar) and a high NH3 uptake of 16.4 mol kg-1 at 298 K and 1 bar for 2.

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A straight forward route for the development of metal-organic frameworks functionalized with aromatic-OH groups: Synthesis, characterization, and gas (N₂, Ar, H₂, CO₂, CH₄, NH ₃) sorption properties

Abstract

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CCDC 870636: Experimental Crystal Structure Determination

CCDC 870637: Experimental Crystal Structure Determination

CCDC 892248: Experimental Crystal Structure Determination

Cite this

A straight forward route for the development of metal-organic frameworks functionalized with aromatic-OH groups: Synthesis, characterization, and gas (N2, Ar, H2, CO2, CH4, NH 3) sorption properties

Abstract

ASJC Scopus subject areas

Access to Document

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Datasets

CCDC 870636: Experimental Crystal Structure Determination

CCDC 870637: Experimental Crystal Structure Determination

CCDC 892248: Experimental Crystal Structure Determination

Cite this

A straight forward route for the development of metal-organic frameworks functionalized with aromatic-OH groups: Synthesis, characterization, and gas (N₂, Ar, H₂, CO₂, CH₄, NH ₃) sorption properties