A supramolecular approach for the formation of fullerene-phthalocyanine dyads

M. Victoria Martínez-Díaz; Nicolette S. Fender; M. Salomé Rodríguez-Morgade; Marcos Gómez-López; François Diederich; Luis Echegoyen; J. Fraser Stoddart; Tomás Torres

doi:10.1039/b110270m

A supramolecular approach for the formation of fullerene-phthalocyanine dyads

M. Victoria Martínez-Díaz, Nicolette S. Fender, M. Salomé Rodríguez-Morgade, Marcos Gómez-López, François Diederich, Luis Echegoyen, J. Fraser Stoddart, Tomás Torres

Chemistry

Research output: Contribution to journal › Article › peer-review

94 Scopus citations

Abstract

A supramolecular Pc-C₆₀ dyad with pseudorotaxane-like geometry has been assembled in solution by the threading of a dibenzylammonium unit attached to a fullerene through the crown ether of an unsymmetrically substituted phthalocyanine, which contains a DB24C8 moiety. Spectroscopic data as well as electrochemical studies suggest a conformation for the complex in which the two bulky subunits are far apart from each other, thus preventing electronic interactions between both electroactive subunits.

Original language	English (US)
Pages (from-to)	2095-2099
Number of pages	5
Journal	Journal of Materials Chemistry
Volume	12
Issue number	7
DOIs	https://doi.org/10.1039/b110270m
State	Published - 2002

ASJC Scopus subject areas

General Chemistry
Materials Chemistry

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title = "A supramolecular approach for the formation of fullerene-phthalocyanine dyads",

abstract = "A supramolecular Pc-C60 dyad with pseudorotaxane-like geometry has been assembled in solution by the threading of a dibenzylammonium unit attached to a fullerene through the crown ether of an unsymmetrically substituted phthalocyanine, which contains a DB24C8 moiety. Spectroscopic data as well as electrochemical studies suggest a conformation for the complex in which the two bulky subunits are far apart from each other, thus preventing electronic interactions between both electroactive subunits.",

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AU - Martínez-Díaz, M. Victoria

AU - Fender, Nicolette S.

AU - Rodríguez-Morgade, M. Salomé

AU - Gómez-López, Marcos

AU - Diederich, François

AU - Echegoyen, Luis

AU - Stoddart, J. Fraser

AU - Torres, Tomás

PY - 2002

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AB - A supramolecular Pc-C60 dyad with pseudorotaxane-like geometry has been assembled in solution by the threading of a dibenzylammonium unit attached to a fullerene through the crown ether of an unsymmetrically substituted phthalocyanine, which contains a DB24C8 moiety. Spectroscopic data as well as electrochemical studies suggest a conformation for the complex in which the two bulky subunits are far apart from each other, thus preventing electronic interactions between both electroactive subunits.

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ER -

A supramolecular approach for the formation of fullerene-phthalocyanine dyads

Abstract

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