Abstract
A supramolecular Pc-C60 dyad with pseudorotaxane-like geometry has been assembled in solution by the threading of a dibenzylammonium unit attached to a fullerene through the crown ether of an unsymmetrically substituted phthalocyanine, which contains a DB24C8 moiety. Spectroscopic data as well as electrochemical studies suggest a conformation for the complex in which the two bulky subunits are far apart from each other, thus preventing electronic interactions between both electroactive subunits.
Original language | English (US) |
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Pages (from-to) | 2095-2099 |
Number of pages | 5 |
Journal | Journal of Materials Chemistry |
Volume | 12 |
Issue number | 7 |
DOIs | |
State | Published - 2002 |
ASJC Scopus subject areas
- General Chemistry
- Materials Chemistry