A supramolecular approach for the formation of fullerene-phthalocyanine dyads

M. Victoria Martínez-Díaz, Nicolette S. Fender, M. Salomé Rodríguez-Morgade, Marcos Gómez-López, François Diederich, Luis Echegoyen, J. Fraser Stoddart, Tomás Torres

Research output: Contribution to journalArticlepeer-review

88 Scopus citations

Abstract

A supramolecular Pc-C60 dyad with pseudorotaxane-like geometry has been assembled in solution by the threading of a dibenzylammonium unit attached to a fullerene through the crown ether of an unsymmetrically substituted phthalocyanine, which contains a DB24C8 moiety. Spectroscopic data as well as electrochemical studies suggest a conformation for the complex in which the two bulky subunits are far apart from each other, thus preventing electronic interactions between both electroactive subunits.

Original languageEnglish (US)
Pages (from-to)2095-2099
Number of pages5
JournalJournal of Materials Chemistry
Volume12
Issue number7
DOIs
StatePublished - Jan 1 2002

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Chemistry

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