A tetranuclear heterobimetallic square formed from the cooperative ligand binding properties of square planar and tetrahedral metal centers

Nathan C. Gianneschi, Chad A. Mirkin*, Lev N. Zakharov, Arnold L. Rheingold

*Corresponding author for this work

Research output: Contribution to journalArticle

23 Scopus citations

Abstract

Reaction of Rh(I) and ZN(II) metal centers with a ligand containing salicylaldiminato and thioether-phosphine moieties resulted in the formation of a tetranuclear heterobimetallic molecular square. The directionality required to form these structures is imparted by both the tetrahedral and square planar metal centers acting in concert with one another.

Original languageEnglish (US)
Pages (from-to)5326-5328
Number of pages3
JournalInorganic chemistry
Volume41
Issue number21
DOIs
StatePublished - Oct 21 2002

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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