A tetranuclear heterobimetallic square formed from the cooperative ligand binding properties of square planar and tetrahedral metal centers

Nathan C. Gianneschi; Chad A. Mirkin; Lev N. Zakharov; Arnold L. Rheingold

doi:10.1021/ic025875o

A tetranuclear heterobimetallic square formed from the cooperative ligand binding properties of square planar and tetrahedral metal centers

Nathan C. Gianneschi, Chad A. Mirkin^*, Lev N. Zakharov, Arnold L. Rheingold

^*Corresponding author for this work

Chemistry

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23 Scopus citations

Abstract

Reaction of Rh(I) and ZN(II) metal centers with a ligand containing salicylaldiminato and thioether-phosphine moieties resulted in the formation of a tetranuclear heterobimetallic molecular square. The directionality required to form these structures is imparted by both the tetrahedral and square planar metal centers acting in concert with one another.

Original language	English (US)
Pages (from-to)	5326-5328
Number of pages	3
Journal	Inorganic chemistry
Volume	41
Issue number	21
DOIs	https://doi.org/10.1021/ic025875o
State	Published - Oct 21 2002

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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abstract = "Reaction of Rh(I) and ZN(II) metal centers with a ligand containing salicylaldiminato and thioether-phosphine moieties resulted in the formation of a tetranuclear heterobimetallic molecular square. The directionality required to form these structures is imparted by both the tetrahedral and square planar metal centers acting in concert with one another.",

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AU - Rheingold, Arnold L.

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AB - Reaction of Rh(I) and ZN(II) metal centers with a ligand containing salicylaldiminato and thioether-phosphine moieties resulted in the formation of a tetranuclear heterobimetallic molecular square. The directionality required to form these structures is imparted by both the tetrahedral and square planar metal centers acting in concert with one another.

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A tetranuclear heterobimetallic square formed from the cooperative ligand binding properties of square planar and tetrahedral metal centers

Abstract

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