A tetranuclear heterobimetallic square formed from the cooperative ligand binding properties of square planar and tetrahedral metal centers

Nathan C. Gianneschi; Chad A. Mirkin; Lev N. Zakharov; Arnold L. Rheingold

doi:10.1021/ic025875o

A tetranuclear heterobimetallic square formed from the cooperative ligand binding properties of square planar and tetrahedral metal centers

Nathan C. Gianneschi, Chad A. Mirkin^*, Lev N. Zakharov, Arnold L. Rheingold

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

Reaction of Rh(I) and ZN(II) metal centers with a ligand containing salicylaldiminato and thioether-phosphine moieties resulted in the formation of a tetranuclear heterobimetallic molecular square. The directionality required to form these structures is imparted by both the tetrahedral and square planar metal centers acting in concert with one another.

Original language	English (US)
Pages (from-to)	5326-5328
Number of pages	3
Journal	Inorganic chemistry
Volume	41
Issue number	21
DOIs	https://doi.org/10.1021/ic025875o
State	Published - Oct 21 2002

ASJC Scopus subject areas

Inorganic Chemistry
Physical and Theoretical Chemistry

Access to Document

10.1021/ic025875o

Cite this

@article{cca31c65d16b4f50bccba63190fbaaa4,

title = "A tetranuclear heterobimetallic square formed from the cooperative ligand binding properties of square planar and tetrahedral metal centers",

abstract = "Reaction of Rh(I) and ZN(II) metal centers with a ligand containing salicylaldiminato and thioether-phosphine moieties resulted in the formation of a tetranuclear heterobimetallic molecular square. The directionality required to form these structures is imparted by both the tetrahedral and square planar metal centers acting in concert with one another.",

author = "Gianneschi, {Nathan C.} and Mirkin, {Chad A.} and Zakharov, {Lev N.} and Rheingold, {Arnold L.}",

year = "2002",

month = oct,

day = "21",

doi = "10.1021/ic025875o",

language = "English (US)",

volume = "41",

pages = "5326--5328",

journal = "Inorganic chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "21",

}

TY - JOUR

T1 - A tetranuclear heterobimetallic square formed from the cooperative ligand binding properties of square planar and tetrahedral metal centers

AU - Gianneschi, Nathan C.

AU - Mirkin, Chad A.

AU - Zakharov, Lev N.

AU - Rheingold, Arnold L.

PY - 2002/10/21

Y1 - 2002/10/21

N2 - Reaction of Rh(I) and ZN(II) metal centers with a ligand containing salicylaldiminato and thioether-phosphine moieties resulted in the formation of a tetranuclear heterobimetallic molecular square. The directionality required to form these structures is imparted by both the tetrahedral and square planar metal centers acting in concert with one another.

AB - Reaction of Rh(I) and ZN(II) metal centers with a ligand containing salicylaldiminato and thioether-phosphine moieties resulted in the formation of a tetranuclear heterobimetallic molecular square. The directionality required to form these structures is imparted by both the tetrahedral and square planar metal centers acting in concert with one another.

UR - http://www.scopus.com/inward/record.url?scp=0037152409&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0037152409&partnerID=8YFLogxK

U2 - 10.1021/ic025875o

DO - 10.1021/ic025875o

M3 - Article

C2 - 12377025

AN - SCOPUS:0037152409

SN - 0020-1669

VL - 41

SP - 5326

EP - 5328

JO - Inorganic chemistry

JF - Inorganic chemistry

IS - 21

ER -

A tetranuclear heterobimetallic square formed from the cooperative ligand binding properties of square planar and tetrahedral metal centers

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

CCDC 189343: Experimental Crystal Structure Determination

Cite this

A tetranuclear heterobimetallic square formed from the cooperative ligand binding properties of square planar and tetrahedral metal centers

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 189343: Experimental Crystal Structure Determination

Cite this