A two-dimensional manganese(II) coordination polymer containing 1-hydroxybenzotriazolate and acetate bridging ligands: Preparation, structural characterization and magnetic study

Constantinos C. Stoumpos; Eleanna Diamantopoulou; Catherine P. Raptopoulou; Aris Terzis; Spyros P. Perlepes; Nikolia Lalioti

doi:10.1016/j.ica.2008.03.071

A two-dimensional manganese(II) coordination polymer containing 1-hydroxybenzotriazolate and acetate bridging ligands: Preparation, structural characterization and magnetic study

Constantinos C. Stoumpos, Eleanna Diamantopoulou, Catherine P. Raptopoulou, Aris Terzis, Spyros P. Perlepes^*, Nikolia Lalioti

^*Corresponding author for this work

Chemistry

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15 Scopus citations

Abstract

The initial use of the 1-hydroxybenzotriazolate (btaO^-)/acetate ligand "blend" in manganese(II) chemistry has yielded a neutral 2D coordination polymer. Complex [Mn₃^II (O₂ CMe)₂ (btaO)₄ (MeOH)₂]_n was prepared by the reaction of Mn(O₂CMe)₂ · 4H₂O with btaOH in MeOH. The structure is based on centrosymmetric trinuclear units, which create the 2D network via 3.1110 and 3.2100 (Harris notation) btaO^- ligands. The two crystallographically independent Mn^II ions within the trinuclear unit are bridged by one 2.11 MeCO₂^- group and two btaO^- ligands. Characteristic IR bands are discussed in terms of the coordination modes of the ligands. The intra- (J₁ = -3.7 cm^-1) and inter (J₂ = J₃ = - 0.2 cm^-1) magnetic exchange coupling constants have been obtained from Monte Carlo calculations.

Original language	English (US)
Pages (from-to)	3638-3645
Number of pages	8
Journal	Inorganica Chimica Acta
Volume	361
Issue number	12-13
DOIs	https://doi.org/10.1016/j.ica.2008.03.071
State	Published - Sep 1 2008

Keywords

Coordination polymers
Crystal structures
Magnetic properties
Manganese(II) 1-hydroxybenzotriazolate complexes
Manganese(II) acetate complexes
Monte Carlo simulation

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.ica.2008.03.071

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Stoumpos, C. C., Diamantopoulou, E., Raptopoulou, C. P., Terzis, A., Perlepes, S. P., & Lalioti, N. (2008). A two-dimensional manganese(II) coordination polymer containing 1-hydroxybenzotriazolate and acetate bridging ligands: Preparation, structural characterization and magnetic study. Inorganica Chimica Acta, 361(12-13), 3638-3645. https://doi.org/10.1016/j.ica.2008.03.071

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title = "A two-dimensional manganese(II) coordination polymer containing 1-hydroxybenzotriazolate and acetate bridging ligands: Preparation, structural characterization and magnetic study",

abstract = "The initial use of the 1-hydroxybenzotriazolate (btaO-)/acetate ligand {"}blend{"} in manganese(II) chemistry has yielded a neutral 2D coordination polymer. Complex [Mn3II (O2 CMe)2 (btaO)4 (MeOH)2]n was prepared by the reaction of Mn(O2CMe)2 · 4H2O with btaOH in MeOH. The structure is based on centrosymmetric trinuclear units, which create the 2D network via 3.1110 and 3.2100 (Harris notation) btaO- ligands. The two crystallographically independent MnII ions within the trinuclear unit are bridged by one 2.11 MeCO2- group and two btaO- ligands. Characteristic IR bands are discussed in terms of the coordination modes of the ligands. The intra- (J1 = -3.7 cm-1) and inter (J2 = J3 = - 0.2 cm-1) magnetic exchange coupling constants have been obtained from Monte Carlo calculations.",

keywords = "Coordination polymers, Crystal structures, Magnetic properties, Manganese(II) 1-hydroxybenzotriazolate complexes, Manganese(II) acetate complexes, Monte Carlo simulation",

author = "Stoumpos, {Constantinos C.} and Eleanna Diamantopoulou and Raptopoulou, {Catherine P.} and Aris Terzis and Perlepes, {Spyros P.} and Nikolia Lalioti",

year = "2008",

month = sep,

day = "1",

doi = "10.1016/j.ica.2008.03.071",

language = "English (US)",

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pages = "3638--3645",

journal = "Inorganica Chimica Acta",

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Stoumpos, CC, Diamantopoulou, E, Raptopoulou, CP, Terzis, A, Perlepes, SP & Lalioti, N 2008, 'A two-dimensional manganese(II) coordination polymer containing 1-hydroxybenzotriazolate and acetate bridging ligands: Preparation, structural characterization and magnetic study', Inorganica Chimica Acta, vol. 361, no. 12-13, pp. 3638-3645. https://doi.org/10.1016/j.ica.2008.03.071

A two-dimensional manganese(II) coordination polymer containing 1-hydroxybenzotriazolate and acetate bridging ligands: Preparation, structural characterization and magnetic study. / Stoumpos, Constantinos C.; Diamantopoulou, Eleanna; Raptopoulou, Catherine P. et al.
In: Inorganica Chimica Acta, Vol. 361, No. 12-13, 01.09.2008, p. 3638-3645.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - A two-dimensional manganese(II) coordination polymer containing 1-hydroxybenzotriazolate and acetate bridging ligands

T2 - Preparation, structural characterization and magnetic study

AU - Stoumpos, Constantinos C.

AU - Diamantopoulou, Eleanna

AU - Raptopoulou, Catherine P.

AU - Terzis, Aris

AU - Perlepes, Spyros P.

AU - Lalioti, Nikolia

PY - 2008/9/1

Y1 - 2008/9/1

N2 - The initial use of the 1-hydroxybenzotriazolate (btaO-)/acetate ligand "blend" in manganese(II) chemistry has yielded a neutral 2D coordination polymer. Complex [Mn3II (O2 CMe)2 (btaO)4 (MeOH)2]n was prepared by the reaction of Mn(O2CMe)2 · 4H2O with btaOH in MeOH. The structure is based on centrosymmetric trinuclear units, which create the 2D network via 3.1110 and 3.2100 (Harris notation) btaO- ligands. The two crystallographically independent MnII ions within the trinuclear unit are bridged by one 2.11 MeCO2- group and two btaO- ligands. Characteristic IR bands are discussed in terms of the coordination modes of the ligands. The intra- (J1 = -3.7 cm-1) and inter (J2 = J3 = - 0.2 cm-1) magnetic exchange coupling constants have been obtained from Monte Carlo calculations.

AB - The initial use of the 1-hydroxybenzotriazolate (btaO-)/acetate ligand "blend" in manganese(II) chemistry has yielded a neutral 2D coordination polymer. Complex [Mn3II (O2 CMe)2 (btaO)4 (MeOH)2]n was prepared by the reaction of Mn(O2CMe)2 · 4H2O with btaOH in MeOH. The structure is based on centrosymmetric trinuclear units, which create the 2D network via 3.1110 and 3.2100 (Harris notation) btaO- ligands. The two crystallographically independent MnII ions within the trinuclear unit are bridged by one 2.11 MeCO2- group and two btaO- ligands. Characteristic IR bands are discussed in terms of the coordination modes of the ligands. The intra- (J1 = -3.7 cm-1) and inter (J2 = J3 = - 0.2 cm-1) magnetic exchange coupling constants have been obtained from Monte Carlo calculations.

KW - Coordination polymers

KW - Crystal structures

KW - Magnetic properties

KW - Manganese(II) 1-hydroxybenzotriazolate complexes

KW - Manganese(II) acetate complexes

KW - Monte Carlo simulation

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DO - 10.1016/j.ica.2008.03.071

M3 - Article

AN - SCOPUS:49049121615

SN - 0020-1693

VL - 361

SP - 3638

EP - 3645

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 12-13

ER -

A two-dimensional manganese(II) coordination polymer containing 1-hydroxybenzotriazolate and acetate bridging ligands: Preparation, structural characterization and magnetic study

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