A Zn-based, pillared paddlewheel MOF containing free carboxylic acids via covalent post-synthesis elaboration

Tendai Gadzikwa; Omar K. Farha; Karen L. Mulfort; Joseph T. Hupp; Sonbinh T. Nguyen

doi:10.1039/b823392f

A Zn-based, pillared paddlewheel MOF containing free carboxylic acids via covalent post-synthesis elaboration

Tendai Gadzikwa, Omar K. Farha, Karen L. Mulfort, Joseph T. Hupp, Sonbinh T. Nguyen

Chemistry

Research output: Contribution to journal › Article › peer-review

143 Scopus citations

Abstract

A Zn-based, mixed-ligand (pillared paddlewheel), metal-organic framework (MOF) has been covalently and quantitatively decorated with free carboxylic acids to demonstrate the utility of covalent post-synthesis modification in the construction of otherwise inaccessible carboxy-functionalized MOFs.

Original language	English (US)
Pages (from-to)	3720-3722
Number of pages	3
Journal	Chemical Communications
Issue number	25
DOIs	https://doi.org/10.1039/b823392f
State	Published - Jul 10 2009

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/b823392f

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abstract = "A Zn-based, mixed-ligand (pillared paddlewheel), metal-organic framework (MOF) has been covalently and quantitatively decorated with free carboxylic acids to demonstrate the utility of covalent post-synthesis modification in the construction of otherwise inaccessible carboxy-functionalized MOFs.",

author = "Tendai Gadzikwa and Farha, {Omar K.} and Mulfort, {Karen L.} and Hupp, {Joseph T.} and Nguyen, {Sonbinh T.}",

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AU - Gadzikwa, Tendai

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AU - Mulfort, Karen L.

AU - Hupp, Joseph T.

AU - Nguyen, Sonbinh T.

PY - 2009/7/10

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AB - A Zn-based, mixed-ligand (pillared paddlewheel), metal-organic framework (MOF) has been covalently and quantitatively decorated with free carboxylic acids to demonstrate the utility of covalent post-synthesis modification in the construction of otherwise inaccessible carboxy-functionalized MOFs.

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A Zn-based, pillared paddlewheel MOF containing free carboxylic acids via covalent post-synthesis elaboration

Abstract

ASJC Scopus subject areas

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