Absorption spectra of intermolecular charge-transfer transitions between xenon and halogen molecules (F2, Cl2, Br2) in liquid xenon

Mario E. Fajardo; V. A. Apkarian; Antonis Moustakas; Herman Krueger; Eric Weitz

doi:10.1021/j100313a023

Absorption spectra of intermolecular charge-transfer transitions between xenon and halogen molecules (F₂, Cl₂, Br₂) in liquid xenon

Mario E. Fajardo, V. A. Apkarian^*, Antonis Moustakas, Herman Krueger, Eric Weitz

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

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Abstract

The intermolecular charge-transfer transitions between molecular halogens, X₂, and Xe can be observed in UV spectra of X₂:Xe liquid solutions (X₂ = F₂, Cl₂, Br₂). In all cases the spectra occur near the UV cutoff of the spectrometer (187 nm). The absorption coefficients at 200 nm are 6.9 × 10^-18,1.2 × 10^-18, and 2.0 × 10^-17 cm² for Xe:F₂, Xe:Cl₂, and Xe:Br₂, respectively. Implications with respect to one-photon- and two-photon-induced cooperative photoproduction of rare gas halides in gas and condensed phases are discussed.

Original language	English (US)
Pages (from-to)	357-360
Number of pages	4
Journal	Journal of physical chemistry
Volume	92
Issue number	2
DOIs	https://doi.org/10.1021/j100313a023
State	Published - 1988

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General Engineering
Physical and Theoretical Chemistry

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@article{4506e42a041e4d5cb8b2b987f9a390f2,

title = "Absorption spectra of intermolecular charge-transfer transitions between xenon and halogen molecules (F2, Cl2, Br2) in liquid xenon",

abstract = "The intermolecular charge-transfer transitions between molecular halogens, X2, and Xe can be observed in UV spectra of X2:Xe liquid solutions (X2 = F2, Cl2, Br2). In all cases the spectra occur near the UV cutoff of the spectrometer (187 nm). The absorption coefficients at 200 nm are 6.9 × 10-18,1.2 × 10-18, and 2.0 × 10-17 cm2 for Xe:F2, Xe:Cl2, and Xe:Br2, respectively. Implications with respect to one-photon- and two-photon-induced cooperative photoproduction of rare gas halides in gas and condensed phases are discussed.",

author = "Fajardo, {Mario E.} and Apkarian, {V. A.} and Antonis Moustakas and Herman Krueger and Eric Weitz",

year = "1988",

doi = "10.1021/j100313a023",

language = "English (US)",

volume = "92",

pages = "357--360",

journal = "Journal of physical chemistry",

issn = "0022-3654",

publisher = "American Chemical Society",

number = "2",

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TY - JOUR

T1 - Absorption spectra of intermolecular charge-transfer transitions between xenon and halogen molecules (F2, Cl2, Br2) in liquid xenon

AU - Fajardo, Mario E.

AU - Apkarian, V. A.

AU - Moustakas, Antonis

AU - Krueger, Herman

AU - Weitz, Eric

PY - 1988

Y1 - 1988

N2 - The intermolecular charge-transfer transitions between molecular halogens, X2, and Xe can be observed in UV spectra of X2:Xe liquid solutions (X2 = F2, Cl2, Br2). In all cases the spectra occur near the UV cutoff of the spectrometer (187 nm). The absorption coefficients at 200 nm are 6.9 × 10-18,1.2 × 10-18, and 2.0 × 10-17 cm2 for Xe:F2, Xe:Cl2, and Xe:Br2, respectively. Implications with respect to one-photon- and two-photon-induced cooperative photoproduction of rare gas halides in gas and condensed phases are discussed.

AB - The intermolecular charge-transfer transitions between molecular halogens, X2, and Xe can be observed in UV spectra of X2:Xe liquid solutions (X2 = F2, Cl2, Br2). In all cases the spectra occur near the UV cutoff of the spectrometer (187 nm). The absorption coefficients at 200 nm are 6.9 × 10-18,1.2 × 10-18, and 2.0 × 10-17 cm2 for Xe:F2, Xe:Cl2, and Xe:Br2, respectively. Implications with respect to one-photon- and two-photon-induced cooperative photoproduction of rare gas halides in gas and condensed phases are discussed.

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U2 - 10.1021/j100313a023

DO - 10.1021/j100313a023

M3 - Article

AN - SCOPUS:0004624637

SN - 0022-3654

VL - 92

SP - 357

EP - 360

JO - Journal of physical chemistry

JF - Journal of physical chemistry

IS - 2

ER -

Absorption spectra of intermolecular charge-transfer transitions between xenon and halogen molecules (F₂, Cl₂, Br₂) in liquid xenon

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