Accessing functionalized porous aromatic frameworks (PAFs) through a de novo approach

Sergio J. Garibay; Mitchell H. Weston; Joseph E. Mondloch; Yamil J. Colón; Omar K. Farha; Joseph T. Hupp; Sonbinh T. Nguyen

doi:10.1039/c2ce26595h

Accessing functionalized porous aromatic frameworks (PAFs) through a de novo approach

Sergio J. Garibay, Mitchell H. Weston, Joseph E. Mondloch, Yamil J. Colón, Omar K. Farha^*, Joseph T. Hupp, Sonbinh T. Nguyen

^*Corresponding author for this work

Chemistry

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71 Scopus citations

Abstract

Methyl-, hydroxymethyl-, and phthalimidomethyl-functionalized versions of the porous organic polymer PAF-1 have been obtained through de novo synthesis. The CO₂ adsorption capacity of PAF-1-CH₂NH₂, obtained through the post-synthesis deprotection of PAF-1-CH₂- phthalimide, has been shown to exceed that of PAF-1.

Original language	English (US)
Pages (from-to)	1515-1519
Number of pages	5
Journal	CrystEngComm
Volume	15
Issue number	8
DOIs	https://doi.org/10.1039/c2ce26595h
State	Published - Feb 28 2013

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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abstract = "Methyl-, hydroxymethyl-, and phthalimidomethyl-functionalized versions of the porous organic polymer PAF-1 have been obtained through de novo synthesis. The CO2 adsorption capacity of PAF-1-CH2NH2, obtained through the post-synthesis deprotection of PAF-1-CH2- phthalimide, has been shown to exceed that of PAF-1.",

author = "Garibay, {Sergio J.} and Weston, {Mitchell H.} and Mondloch, {Joseph E.} and Col{\'o}n, {Yamil J.} and Farha, {Omar K.} and Hupp, {Joseph T.} and Nguyen, {Sonbinh T.}",

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AU - Garibay, Sergio J.

AU - Weston, Mitchell H.

AU - Mondloch, Joseph E.

AU - Colón, Yamil J.

AU - Farha, Omar K.

AU - Hupp, Joseph T.

AU - Nguyen, Sonbinh T.

PY - 2013/2/28

Y1 - 2013/2/28

N2 - Methyl-, hydroxymethyl-, and phthalimidomethyl-functionalized versions of the porous organic polymer PAF-1 have been obtained through de novo synthesis. The CO2 adsorption capacity of PAF-1-CH2NH2, obtained through the post-synthesis deprotection of PAF-1-CH2- phthalimide, has been shown to exceed that of PAF-1.

AB - Methyl-, hydroxymethyl-, and phthalimidomethyl-functionalized versions of the porous organic polymer PAF-1 have been obtained through de novo synthesis. The CO2 adsorption capacity of PAF-1-CH2NH2, obtained through the post-synthesis deprotection of PAF-1-CH2- phthalimide, has been shown to exceed that of PAF-1.

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Accessing functionalized porous aromatic frameworks (PAFs) through a de novo approach

Abstract

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