Acetylene absorption and binding in a nonporous crystal lattice

Praveen K. Thallapally*, Liliana Dobrzańska, Todd R. Gingrich, Trevor B. Wirsig, Leonard J. Barbour, Jerry L. Atwood

*Corresponding author for this work

Research output: Contribution to journalArticle

102 Scopus citations

Abstract

Unusual storage: An organic nonporous material, p-tert-butylcalix[4]arene, sorbs acetylene with high storage density under ambient conditions. It is presumed that gas molecules diffuse through the seemingly nonporous lattice without disrupting the arrangement of the host molecules (see picture; red O, blue C, gray H, yellow void space). (Figure Presented)

Original languageEnglish (US)
Pages (from-to)6506-6509
Number of pages4
JournalAngewandte Chemie - International Edition
Volume45
Issue number39
DOIs
StatePublished - Oct 6 2006

Keywords

  • Acetylene
  • Calixarenes
  • Nonporous materials
  • Sorption
  • Supramolecular chemistry

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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  • Cite this

    Thallapally, P. K., Dobrzańska, L., Gingrich, T. R., Wirsig, T. B., Barbour, L. J., & Atwood, J. L. (2006). Acetylene absorption and binding in a nonporous crystal lattice. Angewandte Chemie - International Edition, 45(39), 6506-6509. https://doi.org/10.1002/anie.200601391