Acid-functionalized dissymmetric salen ligands and their manganese(III) complexes

You Moon Jeon; Jungseok Heo; Chad A. Mirkin

doi:10.1016/j.tetlet.2007.01.023

Acid-functionalized dissymmetric salen ligands and their manganese(III) complexes

You Moon Jeon, Jungseok Heo, Chad A. Mirkin^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

Acid-functionalized symmetric and dissymmetric salen-type ligands were synthesized via a novel self-protection step in a quantitative yield. This synthetic method allows one to quickly prepare salen-based dissymmetric chiral compounds with tailorable coordinating properties. Therefore, this approach provides a blueprint for synthesizing and evaluating a new class of acid-functionalized salen ligands that can be used as chiral building blocks for a wide range of catalysts and coordination polymers with chemically tailorable properties.

Original language	English (US)
Pages (from-to)	2591-2595
Number of pages	5
Journal	Tetrahedron Letters
Volume	48
Issue number	14
DOIs	https://doi.org/10.1016/j.tetlet.2007.01.023
State	Published - Apr 2 2007

Funding

CAM acknowledges the NSF and ARO for the support of this work.

Keywords

Catalyst
Coordination
Dissymmetric
MOF
Metal-organic-framework
Salen
Self-protection

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/j.tetlet.2007.01.023

Cite this

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title = "Acid-functionalized dissymmetric salen ligands and their manganese(III) complexes",

abstract = "Acid-functionalized symmetric and dissymmetric salen-type ligands were synthesized via a novel self-protection step in a quantitative yield. This synthetic method allows one to quickly prepare salen-based dissymmetric chiral compounds with tailorable coordinating properties. Therefore, this approach provides a blueprint for synthesizing and evaluating a new class of acid-functionalized salen ligands that can be used as chiral building blocks for a wide range of catalysts and coordination polymers with chemically tailorable properties.",

keywords = "Catalyst, Coordination, Dissymmetric, MOF, Metal-organic-framework, Salen, Self-protection",

author = "Jeon, {You Moon} and Jungseok Heo and Mirkin, {Chad A.}",

year = "2007",

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language = "English (US)",

volume = "48",

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journal = "Tetrahedron Letters",

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T1 - Acid-functionalized dissymmetric salen ligands and their manganese(III) complexes

AU - Jeon, You Moon

AU - Heo, Jungseok

AU - Mirkin, Chad A.

PY - 2007/4/2

Y1 - 2007/4/2

N2 - Acid-functionalized symmetric and dissymmetric salen-type ligands were synthesized via a novel self-protection step in a quantitative yield. This synthetic method allows one to quickly prepare salen-based dissymmetric chiral compounds with tailorable coordinating properties. Therefore, this approach provides a blueprint for synthesizing and evaluating a new class of acid-functionalized salen ligands that can be used as chiral building blocks for a wide range of catalysts and coordination polymers with chemically tailorable properties.

AB - Acid-functionalized symmetric and dissymmetric salen-type ligands were synthesized via a novel self-protection step in a quantitative yield. This synthetic method allows one to quickly prepare salen-based dissymmetric chiral compounds with tailorable coordinating properties. Therefore, this approach provides a blueprint for synthesizing and evaluating a new class of acid-functionalized salen ligands that can be used as chiral building blocks for a wide range of catalysts and coordination polymers with chemically tailorable properties.

KW - Catalyst

KW - Coordination

KW - Dissymmetric

KW - MOF

KW - Metal-organic-framework

KW - Salen

KW - Self-protection

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M3 - Article

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SN - 0040-4039

VL - 48

SP - 2591

EP - 2595

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 14

ER -

Acid-functionalized dissymmetric salen ligands and their manganese(III) complexes

Abstract

Funding

Keywords

ASJC Scopus subject areas

Access to Document

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CCDC 623453: Experimental Crystal Structure Determination

Cite this

Acid-functionalized dissymmetric salen ligands and their manganese(III) complexes

Abstract

Funding

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 623453: Experimental Crystal Structure Determination

Cite this