TY - JOUR
T1 - Acid-induced conversions in open-framework semiconductors
T2 - From [Cd 4Sn3Se13]6- to [Cd 15Sn12Se46]14-, a remarkable disassembly/reassembly process
AU - Ding, Nan
AU - Kanatzidis, Mercouri G.
PY - 2006/2/20
Y1 - 2006/2/20
N2 - Swapping structures and cations: In an acid-induced 3D-to-3D transformation at room temperature, K6Cd4Sn3Se13 is converted into K14-xHxCd15Sn 12Se46. The [Cd15Sn12Se 46]14- framework, which contains a tunnel network of accessible cages of labyrinthine complexity (see picture), is highly robust, acid resistant, and has excellent ion-exchange properties. (Figure Presented)
AB - Swapping structures and cations: In an acid-induced 3D-to-3D transformation at room temperature, K6Cd4Sn3Se13 is converted into K14-xHxCd15Sn 12Se46. The [Cd15Sn12Se 46]14- framework, which contains a tunnel network of accessible cages of labyrinthine complexity (see picture), is highly robust, acid resistant, and has excellent ion-exchange properties. (Figure Presented)
KW - Chalcogenides
KW - Hydrothermal synthesis
KW - Ion-exchange
KW - Open-framework structures
KW - Semiconductors
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U2 - 10.1002/anie.200502787
DO - 10.1002/anie.200502787
M3 - Article
C2 - 16425334
AN - SCOPUS:33745938479
SN - 1433-7851
VL - 45
SP - 1397
EP - 1401
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 9
ER -