Adding to the Arsenal of Zirconium-Based Metal–Organic Frameworks: the Topology as a Platform for Solvent-Assisted Metal Incorporation

Tian Fu Liu; Nicolaas A. Vermeulen; Ashlee J. Howarth; Peng Li; Amy A. Sarjeant; Joseph T. Hupp; Omar K. Farha

doi:10.1002/ejic.201600627

Adding to the Arsenal of Zirconium-Based Metal–Organic Frameworks: the Topology as a Platform for Solvent-Assisted Metal Incorporation

Tian Fu Liu, Nicolaas A. Vermeulen, Ashlee J. Howarth, Peng Li, Amy A. Sarjeant, Joseph T. Hupp, Omar K. Farha^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

59 Scopus citations

Abstract

Gaining control over the assembly of mesoporous Zr-based metal–organic frameworks (MOFs) with modifiable metal nodes remains a challenge. The the topology is intriguing, particularly if considering postsynthetic modification, as it presents large sodalite-like cages surrounded by 12 interconnected 1D channels that allow for efficient diffusion of guest molecules throughout the structure. Herein, we demonstrate the first Zr MOF with the topology, NU-1200, which was synthesized by controlling the geometry of the organic building unit. In addition, by using NU-1200 as a platform, we perform solvent-assisted metal incorporation to form single-site metalated nodes, a process that is characterized by single-crystal X-ray diffraction.

Original language	English (US)
Pages (from-to)	4349-4352
Number of pages	4
Journal	European Journal of Inorganic Chemistry
Volume	2016
Issue number	27
DOIs	https://doi.org/10.1002/ejic.201600627
State	Published - Sep 2016

Funding

O. K. F. and J. T. H. gratefully acknowledge support from the Inorganometallic Catalyst Design Center, an Energy Frontier Research Center, funded by the U. S. Department of Energy, Office of Science, Basic Energy Sciences, under Award DESC0012702. This work made use of the J. B. Cohen X-ray Diffraction Facility supported by the MRSEC program of the National Science Foundation (DMR-1121262) at the Materials Research Center of Northwestern University.

Keywords

Cluster compounds
Geometry
Metal–organic frameworks
Topology
Zirconium

ASJC Scopus subject areas

Inorganic Chemistry

Access to Document

10.1002/ejic.201600627

Cite this

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title = "Adding to the Arsenal of Zirconium-Based Metal–Organic Frameworks: the Topology as a Platform for Solvent-Assisted Metal Incorporation",

abstract = "Gaining control over the assembly of mesoporous Zr-based metal–organic frameworks (MOFs) with modifiable metal nodes remains a challenge. The the topology is intriguing, particularly if considering postsynthetic modification, as it presents large sodalite-like cages surrounded by 12 interconnected 1D channels that allow for efficient diffusion of guest molecules throughout the structure. Herein, we demonstrate the first Zr MOF with the topology, NU-1200, which was synthesized by controlling the geometry of the organic building unit. In addition, by using NU-1200 as a platform, we perform solvent-assisted metal incorporation to form single-site metalated nodes, a process that is characterized by single-crystal X-ray diffraction.",

keywords = "Cluster compounds, Geometry, Metal–organic frameworks, Topology, Zirconium",

author = "Liu, {Tian Fu} and Vermeulen, {Nicolaas A.} and Howarth, {Ashlee J.} and Peng Li and Sarjeant, {Amy A.} and Hupp, {Joseph T.} and Farha, {Omar K.}",

note = "Publisher Copyright: {\textcopyright} 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim",

year = "2016",

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language = "English (US)",

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T2 - the Topology as a Platform for Solvent-Assisted Metal Incorporation

AU - Liu, Tian Fu

AU - Vermeulen, Nicolaas A.

AU - Howarth, Ashlee J.

AU - Li, Peng

AU - Sarjeant, Amy A.

AU - Hupp, Joseph T.

AU - Farha, Omar K.

PY - 2016/9

Y1 - 2016/9

N2 - Gaining control over the assembly of mesoporous Zr-based metal–organic frameworks (MOFs) with modifiable metal nodes remains a challenge. The the topology is intriguing, particularly if considering postsynthetic modification, as it presents large sodalite-like cages surrounded by 12 interconnected 1D channels that allow for efficient diffusion of guest molecules throughout the structure. Herein, we demonstrate the first Zr MOF with the topology, NU-1200, which was synthesized by controlling the geometry of the organic building unit. In addition, by using NU-1200 as a platform, we perform solvent-assisted metal incorporation to form single-site metalated nodes, a process that is characterized by single-crystal X-ray diffraction.

AB - Gaining control over the assembly of mesoporous Zr-based metal–organic frameworks (MOFs) with modifiable metal nodes remains a challenge. The the topology is intriguing, particularly if considering postsynthetic modification, as it presents large sodalite-like cages surrounded by 12 interconnected 1D channels that allow for efficient diffusion of guest molecules throughout the structure. Herein, we demonstrate the first Zr MOF with the topology, NU-1200, which was synthesized by controlling the geometry of the organic building unit. In addition, by using NU-1200 as a platform, we perform solvent-assisted metal incorporation to form single-site metalated nodes, a process that is characterized by single-crystal X-ray diffraction.

KW - Cluster compounds

KW - Geometry

KW - Metal–organic frameworks

KW - Topology

KW - Zirconium

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Adding to the Arsenal of Zirconium-Based Metal–Organic Frameworks: the Topology as a Platform for Solvent-Assisted Metal Incorporation

Abstract

Funding

Keywords

ASJC Scopus subject areas

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CCDC 1481852: Experimental Crystal Structure Determination

CCDC 1481853: Experimental Crystal Structure Determination

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Adding to the Arsenal of Zirconium-Based Metal–Organic Frameworks: the Topology as a Platform for Solvent-Assisted Metal Incorporation

Abstract

Funding

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 1481852: Experimental Crystal Structure Determination

CCDC 1481853: Experimental Crystal Structure Determination

Cite this