Adsorption of light gases in large-pore isoreticular metal organic frameworks

Youn Sang Bae; Andrew Nelson; David Dubbeldam; Houston Frost; Joseph T. Hupp; Randall Q. Snurr

Adsorption of light gases in large-pore isoreticular metal organic frameworks

Youn Sang Bae^*, Andrew Nelson, David Dubbeldam, Houston Frost, Joseph T. Hupp, Randall Q. Snurr

^*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Abstract

Metal-organic frameworks (MOF) have emerged as promising materials for separations, gas storage, catalysis, and chemical sensing. One class of widely-studied MOF are the isoreticular metal-organic frameworks (IRMOF), discovered by Yaghi et al. Several large-pore IRMOFs were synthesized by the solvothermal method. Two solvent removal procedures were compared, i.e., the original method involving chloroform exchange suggested by Yaghi and a newly developed procedure. The adsorption properties of light gases, e.g., H₂ and CO₂, on IRMOF was examined. Grand canonical Monte Carlo simulations of light gases, with and without co-adsorbed solvent molecules, were used to help understand and interpret the experimental results. This is an abstract of a paper presented at the 2007 AIChE Annual Meeting (Salt Lake City, UT 11/4-9/2007).

Original language	English (US)
Title of host publication	2007 AIChE Annual Meeting
State	Published - 2007
Event	2007 AIChE Annual Meeting - Salt Lake City, UT, United States Duration: Nov 4 2007 → Nov 9 2007

Publication series

Name	2007 AIChE Annual Meeting

Other

Other	2007 AIChE Annual Meeting
Country/Territory	United States
City	Salt Lake City, UT
Period	11/4/07 → 11/9/07

ASJC Scopus subject areas

Biotechnology
General Chemical Engineering
Bioengineering
Safety, Risk, Reliability and Quality

Cite this

@inproceedings{b00975003c374e23993050c2cd006873,

title = "Adsorption of light gases in large-pore isoreticular metal organic frameworks",

abstract = "Metal-organic frameworks (MOF) have emerged as promising materials for separations, gas storage, catalysis, and chemical sensing. One class of widely-studied MOF are the isoreticular metal-organic frameworks (IRMOF), discovered by Yaghi et al. Several large-pore IRMOFs were synthesized by the solvothermal method. Two solvent removal procedures were compared, i.e., the original method involving chloroform exchange suggested by Yaghi and a newly developed procedure. The adsorption properties of light gases, e.g., H2 and CO2, on IRMOF was examined. Grand canonical Monte Carlo simulations of light gases, with and without co-adsorbed solvent molecules, were used to help understand and interpret the experimental results. This is an abstract of a paper presented at the 2007 AIChE Annual Meeting (Salt Lake City, UT 11/4-9/2007).",

author = "Bae, {Youn Sang} and Andrew Nelson and David Dubbeldam and Houston Frost and Hupp, {Joseph T.} and Snurr, {Randall Q.}",

year = "2007",

language = "English (US)",

isbn = "9780816910229",

series = "2007 AIChE Annual Meeting",

booktitle = "2007 AIChE Annual Meeting",

note = "2007 AIChE Annual Meeting ; Conference date: 04-11-2007 Through 09-11-2007",

}

TY - GEN

T1 - Adsorption of light gases in large-pore isoreticular metal organic frameworks

AU - Bae, Youn Sang

AU - Nelson, Andrew

AU - Dubbeldam, David

AU - Frost, Houston

AU - Hupp, Joseph T.

AU - Snurr, Randall Q.

PY - 2007

Y1 - 2007

N2 - Metal-organic frameworks (MOF) have emerged as promising materials for separations, gas storage, catalysis, and chemical sensing. One class of widely-studied MOF are the isoreticular metal-organic frameworks (IRMOF), discovered by Yaghi et al. Several large-pore IRMOFs were synthesized by the solvothermal method. Two solvent removal procedures were compared, i.e., the original method involving chloroform exchange suggested by Yaghi and a newly developed procedure. The adsorption properties of light gases, e.g., H2 and CO2, on IRMOF was examined. Grand canonical Monte Carlo simulations of light gases, with and without co-adsorbed solvent molecules, were used to help understand and interpret the experimental results. This is an abstract of a paper presented at the 2007 AIChE Annual Meeting (Salt Lake City, UT 11/4-9/2007).

AB - Metal-organic frameworks (MOF) have emerged as promising materials for separations, gas storage, catalysis, and chemical sensing. One class of widely-studied MOF are the isoreticular metal-organic frameworks (IRMOF), discovered by Yaghi et al. Several large-pore IRMOFs were synthesized by the solvothermal method. Two solvent removal procedures were compared, i.e., the original method involving chloroform exchange suggested by Yaghi and a newly developed procedure. The adsorption properties of light gases, e.g., H2 and CO2, on IRMOF was examined. Grand canonical Monte Carlo simulations of light gases, with and without co-adsorbed solvent molecules, were used to help understand and interpret the experimental results. This is an abstract of a paper presented at the 2007 AIChE Annual Meeting (Salt Lake City, UT 11/4-9/2007).

UR - http://www.scopus.com/inward/record.url?scp=58049087733&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=58049087733&partnerID=8YFLogxK

M3 - Conference contribution

AN - SCOPUS:58049087733

SN - 9780816910229

T3 - 2007 AIChE Annual Meeting

BT - 2007 AIChE Annual Meeting

T2 - 2007 AIChE Annual Meeting

Y2 - 4 November 2007 through 9 November 2007

ER -

Adsorption of light gases in large-pore isoreticular metal organic frameworks

Abstract

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