Adsorption of rod-like polyelectrolytes onto weakly charged surfaces

Hao Cheng, M Olvera de la Cruz*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

30 Scopus citations

Abstract

Adsorption of strongly charged rods including lateral correlations and equating the chemical potentials of the free and adsorbed rods and of the free and condensed counterions allowed to self-consistently determine the fraction of monomers with condensed counterions for rods in the bulk solution and for rods adsorbed on the surface. The radius of the surface pattern of adsorbed rods decreased as the salt concentration increased.

Original languageEnglish (US)
Pages (from-to)12635-12644
Number of pages10
JournalJournal of Chemical Physics
Volume119
Issue number23
DOIs
StatePublished - Dec 15 2003

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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