Ag-Cu-Ti braze materials for sealing SOFCs

Worawarit Kobsiriphat*, Scott Barnett

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

29 Scopus citations


Two Ag-Cu-Ti brazing alloy compositions were studied as gas seals for solid oxide fuel cells (SOFCs). Yttia-stabilized zirconia pellets were bonded using Ag-35.25Cu-1.75Ti (Cusil-ABA) or Ag-20.1Cu-1.0Ti (average composition; Ag-Cusil). Both as-brazed filler metals contained metallic Ag and Cu phases, along with continuous titanium oxide layers at the filler metal-zirconia interfaces. The brazed joints were then aged at 700°C for up to 100 h in air or while separating H2 and air atmospheres. After annealing in air for 100 h at 700°C, degradation in microstructure and hermeticily was more pronounced in Cusil-ABA. However in H2-air atmosphere, Cusil-ABA performed better than Ag-Cusil. Ag-Cusil aged in H2 air delaminated from zirconia and its microstructure showed large interconnected pores in Ag-rich regions. The results were confirmed by single-cell tests using each filler metal as a gas seal. Observations of the post-test Cusil-ABA microstructure revealed little degradation. These results indicate that Cusil-ABA is better suited than Ag-Cusil as a SOFC gas seal.

Original languageEnglish (US)
Article number011002
JournalJournal of Fuel Cell Science and Technology
Issue number1
StatePublished - Feb 2008

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Energy Engineering and Power Technology
  • Mechanics of Materials
  • Mechanical Engineering


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