Alkali and alkaline earth metal ion-sensing studies on two disubstituted diphenyl ethers of tetraethylene glycol

G. J. Moody; Bahruddin B. Saad; J. D R Thomas; F. H. Kohnket; J. F. Stoddart

doi:10.1039/AN9881301295

Alkali and alkaline earth metal ion-sensing studies on two disubstituted diphenyl ethers of tetraethylene glycol

G. J. Moody, Bahruddin B. Saad, J. D R Thomas, F. H. Kohnket, J. F. Stoddart

Chemistry

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

The acyclic polyethers 1,11-bis(2-hydroxy-5-formylphenoxy)-3,6,9- trioxaundecane (1) and its dibenzyl ether (2) were evaluated individually, when incorporated with seven different solvent mediators and, in some instances, also with an anion excluder, as possible alkali and alkaline earth metal ion sensors. The response characteristics of the diphenol 1 are more dependent on the solvent mediator used whereas the dibenzyl ether 2 shows a preferential response towards potassium ions regardless of the solvent mediator used. The solvent mediators themselves were also checked for their ion-sensing qualities: tris(2-ethylhexyl) phosphate and dioctyl phenylphosphonate both exhibit a substantial response towards lithium ions; dioctyl sebacate, dibutyl phthalate and bis(2-ethylhexyl) adipate all show some response towards potassium ions.

Original language	English (US)
Pages (from-to)	1295-1298
Number of pages	4
Journal	The Analyst
Volume	113
DOIs	https://doi.org/10.1039/AN9881301295
State	Published - 1988

Keywords

Acyclic polyethers
Neutral and diphenolic carriers
Pvc matrix ion-selective electrodes
Solvent mediators

ASJC Scopus subject areas

Analytical Chemistry
Biochemistry
Environmental Chemistry
Spectroscopy
Electrochemistry

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10.1039/AN9881301295

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title = "Alkali and alkaline earth metal ion-sensing studies on two disubstituted diphenyl ethers of tetraethylene glycol",

abstract = "The acyclic polyethers 1,11-bis(2-hydroxy-5-formylphenoxy)-3,6,9- trioxaundecane (1) and its dibenzyl ether (2) were evaluated individually, when incorporated with seven different solvent mediators and, in some instances, also with an anion excluder, as possible alkali and alkaline earth metal ion sensors. The response characteristics of the diphenol 1 are more dependent on the solvent mediator used whereas the dibenzyl ether 2 shows a preferential response towards potassium ions regardless of the solvent mediator used. The solvent mediators themselves were also checked for their ion-sensing qualities: tris(2-ethylhexyl) phosphate and dioctyl phenylphosphonate both exhibit a substantial response towards lithium ions; dioctyl sebacate, dibutyl phthalate and bis(2-ethylhexyl) adipate all show some response towards potassium ions.",

keywords = "Acyclic polyethers, Neutral and diphenolic carriers, Pvc matrix ion-selective electrodes, Solvent mediators",

author = "Moody, {G. J.} and Saad, {Bahruddin B.} and Thomas, {J. D R} and Kohnket, {F. H.} and Stoddart, {J. F.}",

year = "1988",

doi = "10.1039/AN9881301295",

language = "English (US)",

volume = "113",

pages = "1295--1298",

journal = "Analyst",

issn = "0003-2654",

publisher = "Royal Society of Chemistry",

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T1 - Alkali and alkaline earth metal ion-sensing studies on two disubstituted diphenyl ethers of tetraethylene glycol

AU - Moody, G. J.

AU - Saad, Bahruddin B.

AU - Thomas, J. D R

AU - Kohnket, F. H.

AU - Stoddart, J. F.

PY - 1988

Y1 - 1988

N2 - The acyclic polyethers 1,11-bis(2-hydroxy-5-formylphenoxy)-3,6,9- trioxaundecane (1) and its dibenzyl ether (2) were evaluated individually, when incorporated with seven different solvent mediators and, in some instances, also with an anion excluder, as possible alkali and alkaline earth metal ion sensors. The response characteristics of the diphenol 1 are more dependent on the solvent mediator used whereas the dibenzyl ether 2 shows a preferential response towards potassium ions regardless of the solvent mediator used. The solvent mediators themselves were also checked for their ion-sensing qualities: tris(2-ethylhexyl) phosphate and dioctyl phenylphosphonate both exhibit a substantial response towards lithium ions; dioctyl sebacate, dibutyl phthalate and bis(2-ethylhexyl) adipate all show some response towards potassium ions.

AB - The acyclic polyethers 1,11-bis(2-hydroxy-5-formylphenoxy)-3,6,9- trioxaundecane (1) and its dibenzyl ether (2) were evaluated individually, when incorporated with seven different solvent mediators and, in some instances, also with an anion excluder, as possible alkali and alkaline earth metal ion sensors. The response characteristics of the diphenol 1 are more dependent on the solvent mediator used whereas the dibenzyl ether 2 shows a preferential response towards potassium ions regardless of the solvent mediator used. The solvent mediators themselves were also checked for their ion-sensing qualities: tris(2-ethylhexyl) phosphate and dioctyl phenylphosphonate both exhibit a substantial response towards lithium ions; dioctyl sebacate, dibutyl phthalate and bis(2-ethylhexyl) adipate all show some response towards potassium ions.

KW - Acyclic polyethers

KW - Neutral and diphenolic carriers

KW - Pvc matrix ion-selective electrodes

KW - Solvent mediators

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JF - Analyst

SN - 0003-2654

ER -

Alkali and alkaline earth metal ion-sensing studies on two disubstituted diphenyl ethers of tetraethylene glycol

Abstract

Keywords

ASJC Scopus subject areas

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