All-solid-state dye-sensitized solar cells with high efficiency

In Chung, Byunghong Lee, Jiaqing He, Robert P.H. Chang, Mercouri G. Kanatzidis*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

1184 Scopus citations

Abstract

Dye-sensitized solar cells based on titanium dioxide (TiO2) are promising low-cost alternatives to conventional solid-state photovoltaic devices based on materials such as Si, CdTe and CuIn1-x Gax Se2 (refs 1, 2). Despite offering relatively high conversion efficiencies for solar energy, typical dye-sensitized solar cells suffer from durability problems that result from their use of organic liquid electrolytes containing the iodide/tri-iodide redox couple, which causes serious problems such as electrode corrosion and electrolyte leakage. Replacements for iodine-based liquid electrolytes have been extensively studied, but the efficiencies of the resulting devices remain low. Here we show that the solution-processable p-type direct bandgap semiconductor CsSnI 3 can be used for hole conduction in lieu of a liquid electrolyte. The resulting solid-state dye-sensitized solar cells consist of CsSnI 2.95 F 0.05 doped with SnF 2, nanoporous TiO2 and the dye N719, and show conversion efficiencies of up to 10.2 per cent (8.51 per cent with a mask). With a bandgap of 1.3 electronvolts, CsSnI 3 enhances visible light absorption on the red side of the spectrum to outperform the typical dye-sensitized solar cells in this spectral region.

Original languageEnglish (US)
Pages (from-to)486-489
Number of pages4
JournalNature
Volume485
Issue number7399
DOIs
StatePublished - May 24 2012

ASJC Scopus subject areas

  • General

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