Amphiphilic perylenetretracarboxyl diimide dimer and its application in field effect transistor

Yanfeng Wang; Yanli Chen; Renjie Li; Shuangqing Wang; Wei Su; Pan Ma; Michael R. Wasielewski; Xiyou Li; Jianzhuang Jiang

doi:10.1021/la063729f

Amphiphilic perylenetretracarboxyl diimide dimer and its application in field effect transistor

Yanfeng Wang, Yanli Chen, Renjie Li, Shuangqing Wang, Wei Su, Pan Ma, Michael R. Wasielewski, Xiyou Li^*, Jianzhuang Jiang

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

68 Scopus citations

Abstract

A novel perylene diimide (PDI) derivative with typical amphiphilic character, 2, was designed and prepared. The spectroscopic studies on this compound in solution revealed the face-to-face dimeric configuration and effective π - π interaction between the two perylene rings. This amphiphilic PDI derivative was fabricated into highly ordered films by Langmuir - Blodgett (LB) technique and fabricated into an organic field effect transistor (OFET), which shows carrier mobility around 0.05 cm² V^-1 s^-1 and current modulation of 10³. This OFET performance is much better than that of monomeric PDI 1 and can be attributed to the unique face-to-face structure of 2, which promotes the interactions between neighboring PDI ring in LB film as indicated by the π - A isotherms and UV - vis absorption.

Original language	English (US)
Pages (from-to)	5836-5842
Number of pages	7
Journal	Langmuir
Volume	23
Issue number	10
DOIs	https://doi.org/10.1021/la063729f
State	Published - May 8 2007

ASJC Scopus subject areas

Materials Science(all)
Condensed Matter Physics
Surfaces and Interfaces
Spectroscopy
Electrochemistry

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10.1021/la063729f

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title = "Amphiphilic perylenetretracarboxyl diimide dimer and its application in field effect transistor",

abstract = "A novel perylene diimide (PDI) derivative with typical amphiphilic character, 2, was designed and prepared. The spectroscopic studies on this compound in solution revealed the face-to-face dimeric configuration and effective π - π interaction between the two perylene rings. This amphiphilic PDI derivative was fabricated into highly ordered films by Langmuir - Blodgett (LB) technique and fabricated into an organic field effect transistor (OFET), which shows carrier mobility around 0.05 cm2 V-1 s-1 and current modulation of 103. This OFET performance is much better than that of monomeric PDI 1 and can be attributed to the unique face-to-face structure of 2, which promotes the interactions between neighboring PDI ring in LB film as indicated by the π - A isotherms and UV - vis absorption.",

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T1 - Amphiphilic perylenetretracarboxyl diimide dimer and its application in field effect transistor

AU - Wang, Yanfeng

AU - Chen, Yanli

AU - Li, Renjie

AU - Wang, Shuangqing

AU - Su, Wei

AU - Ma, Pan

AU - Wasielewski, Michael R.

AU - Li, Xiyou

AU - Jiang, Jianzhuang

PY - 2007/5/8

Y1 - 2007/5/8

N2 - A novel perylene diimide (PDI) derivative with typical amphiphilic character, 2, was designed and prepared. The spectroscopic studies on this compound in solution revealed the face-to-face dimeric configuration and effective π - π interaction between the two perylene rings. This amphiphilic PDI derivative was fabricated into highly ordered films by Langmuir - Blodgett (LB) technique and fabricated into an organic field effect transistor (OFET), which shows carrier mobility around 0.05 cm2 V-1 s-1 and current modulation of 103. This OFET performance is much better than that of monomeric PDI 1 and can be attributed to the unique face-to-face structure of 2, which promotes the interactions between neighboring PDI ring in LB film as indicated by the π - A isotherms and UV - vis absorption.

AB - A novel perylene diimide (PDI) derivative with typical amphiphilic character, 2, was designed and prepared. The spectroscopic studies on this compound in solution revealed the face-to-face dimeric configuration and effective π - π interaction between the two perylene rings. This amphiphilic PDI derivative was fabricated into highly ordered films by Langmuir - Blodgett (LB) technique and fabricated into an organic field effect transistor (OFET), which shows carrier mobility around 0.05 cm2 V-1 s-1 and current modulation of 103. This OFET performance is much better than that of monomeric PDI 1 and can be attributed to the unique face-to-face structure of 2, which promotes the interactions between neighboring PDI ring in LB film as indicated by the π - A isotherms and UV - vis absorption.

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Amphiphilic perylenetretracarboxyl diimide dimer and its application in field effect transistor

Abstract

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